Chromium contamination in groundwater and Sobol sensitivity model based human health risk evaluation from leather tanning industrial region of South India

The present investigation was conducted to find the possible chromium contamination in groundwater and the related health risks in a leather industrial region of south India using Sobol sensitivity modeling. Thirty-five groundwater samples were sampled from the field sites and were analyzed for pH, TDS (Total Dissolved Solids), EC (Electrical Conductivity), F- (Fluoride), NO3- (Nitrate) and Cr (Chromium). The concentration of nitrate varied from 3 to 81 mg/L with a mean of 48.6 mg/L. About 57% (n = 20) of the wells surpassed the drinkable limit (45 mg/L) for NO3- as per World Health Organization (WHO). The fluoride ion ranged from 0.1 to 2.7 mg/L with a mean of 1.5 mg/L. Around 51% (n = 18) of the samples crossed the recommended limit of WHO for F- (1.5 mg/L). The chromium varied from 0.01 to 0.19 mg/L in groundwater with a mean of 0.1 mg/L. About 66% (n = 23) of the samples overshoot the permissible limit of WHO standards (0.05 mg/L) for Cr. The spatial distribution map of chromium in the groundwater showed that 271.76 km(2) area is under risk. Based on total hazard index (THI), 66%, 46%, and 43% of the groundwater samples surpassed the allowable limit (THI > 1) for children, women and men, correspondingly. Children pose severe health risks than women and men in this region. Using Sobol sensitivity indices, three different categories of risk effects were assessed: first order effect (FOE), total effect (TE) and second order effect (SOE). In the oral sensitivity model, concentration of Cr (C-w) in water and ingestion rate (IR) had the dominant role, whereas in the dermal model, skin surface area (SA) and contact fraction by skin (F) had vital role in addition to the concentration (C-w). Further, the outcome of this study insists the responsibilities of industrial, municipal and agricultural sectors to keep the environment pollution free and to ensure the supply of potable water to the people.