Synthesis and Self-Association of Organoplatinum(IV) Boronic Acids

被引：14
|
作者：
Safa, Muhieddine A. [1 ]
Abo-Amer, Anwar [1 ,2 ]
Borecki, Aneta [1 ]
Cooper, Benjamin F. T. [1 ]
Puddephatt, Richard J. [1 ]
机构：
[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
[2] Al Al Bayt Univ, Dept Chem, Al Mafraq, Jordan
来源：
ORGANOMETALLICS | 2012年 / 31卷 / 07期
基金：
加拿大自然科学与工程研究理事会;
关键词：
HYDROGEN-BONDED NETWORKS; MOLECULAR-COMPLEXES; PLATINUM COMPLEXES; PHENYLBORONIC ACID; BONDING GROUPS; REACTIVITY; SALTS; DERIVATIVES; BINUCLEAR; CHEMISTRY;
D O I：
10.1021/om2009217
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Oxidative addition of ortho, meta, and para isomers of BrCH2C6H4B(OH)(2) to dimethylplatinum(II) complexes gave the corresponding organoplatinum(IV) boronic acids [PtBrMe2{CH2C6H4B(OH)(2)}(NN)], with the bidentate ligand NN = 4,4'-bis(ethoxycarbonyl)-2,2'-bipyridine or 2,5-bis(2-pyridyl)-1,3,4-oxadiazole. The complexes undergo self-assembly in the solid state through hydrogen bonding to give dimers, polymers, or sheet structures.
引用
收藏
页码：2675 / 2681
页数：7
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