Visible Light Organic Photoredox-Catalyzed C-H Alkoxylation of Imidazopyridine with Alcohol

被引：76

作者：

Kibriya, Golam ^{[1
]}

Samanta, Sadhanendu ^{[1
]}

Jana, Sourav ^{[1
]}

Mondal, Susmita ^{[1
]}

Hajra, Alakananda ^{[1
]}

机构：

[1] Visva Bharati, Dept Chem, Santini Ketan 731235, W Bengal, India

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 82卷 / 24期

关键词：

ROOM-TEMPERATURE; IMIDAZOHETEROCYCLES; FUNCTIONALIZATION; ETHERS; SULFENYLATION; OXIDANT; DESIGN;

D O I：

10.1021/acs.joc.7b02582

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The visible light-mediated C-3 alkoxylation of imidazopyridines with alcohols has been achieved using rose bengal as an organic photoredox catalyst at room temperature. Widely abundant air acts as the terminal oxidant that avoids the use of a stoichiometric amount of peroxo compounds. A wide range of functional groups could be tolerated under the reaction conditions to produce C(sp(2))-H alkoxylated products in high yields.

引用

页码：13722 / 13727

页数：6

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