Excited-state reversible geminate reaction. II. Contact geminate quenching

被引:51
|
作者
Agmon, N [1 ]
机构
[1] Hebrew Univ Jerusalem, Dept Phys Chem, Fritz Haber Res Ctr, IL-91904 Jerusalem, Israel
来源
JOURNAL OF CHEMICAL PHYSICS | 1999年 / 110卷 / 04期
关键词
D O I
10.1063/1.477828
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Results of Part I are extended to include the effect of contact quenching by the geminate partner. The long-time and asymptotic solutions derived herein are compared with numerical and experimental data for excited-state proton transfer to solvent, involving both quenching and two different lifetimes. (C) 1999 American Institute of Physics. [S0021-9606(99)51104-5].
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页码:2175 / 2180
页数:6
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