Mechanism and kinetics of methanol synthesis coupled with water-gas shift reaction.

被引：0

作者：

Lin, GI ^{[1
]}

Kotyaev, KP ^{[1
]}

Rozovskii, AY ^{[1
]}

机构：

[1] Russian Acad Sci, AV Topchiev Petrochem Synth Inst, Moscow 117912, Russia

来源：

KINETICS AND CATALYSIS | 1998年 / 39卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The experimental data are reported on the kinetics of methanol synthesis and water-gas shift reaction. Under certain conditions of methanol synthesis, some anomalous kinetics was observed: an increase in the average rate of the reaction in the integral flow-type reactor with an increase in the contact time. This unusual behavior is stipulated by the coupling of methanol synthesis with the water-gas shift reaction. A modified scheme of the mechanism is proposed that accounts for this coupling.

引用

页码：798 / 802

页数：5

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