Study on preparation technology of porous hollow oxidation fiber based on ultrahigh molecular weight polyacrylonitrile
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作者:
Shen, XY
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China Text Univ, Coll Mat Sci & Engn, State Key Lab Modificat Fiber Mat, Shanghai 200051, Peoples R ChinaChina Text Univ, Coll Mat Sci & Engn, State Key Lab Modificat Fiber Mat, Shanghai 200051, Peoples R China
Shen, XY
[1
]
Wang, QR
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机构:
China Text Univ, Coll Mat Sci & Engn, State Key Lab Modificat Fiber Mat, Shanghai 200051, Peoples R ChinaChina Text Univ, Coll Mat Sci & Engn, State Key Lab Modificat Fiber Mat, Shanghai 200051, Peoples R China
Wang, QR
[1
]
机构:
[1] China Text Univ, Coll Mat Sci & Engn, State Key Lab Modificat Fiber Mat, Shanghai 200051, Peoples R China
The preparation of a kind of porous hollow oxidation fiber based on ultrahigh molecular weight polyacrylonitrile ( UHMW-PAN) as precursor is presented. The effects of preparation technology conditions, oxidation temperature and oxidation time, on degree of ring formation of porous hollow oxidation fiber are studied in details. It shows that degree of ring formation is increasing with increasing of oxidation temperature and time. Comparing with normal molecular weight polyacrylonitrile (CMW-PAN) based solid fibers, the oxidation temperature of porous hollow fiber based on UHMW-PAN should be low (< 240 degreesC) and oxidation time should be short (< 2 h).