Mixing enthalpies of liquid Au-Ga-In alloys

被引:6
|
作者
Jendrzejczyk-Handzlik, Dominika [1 ]
Handzlik, Piotr [1 ]
机构
[1] AGH Univ Sci & Technol, Fac Nonferrous Met, Krakow 30 Mickiewicza Ave, PL-30059 Krakow, Poland
关键词
Au-Ga-In alloys; Mixing enthalpy; Calorimetry; Thermochemistry; GALLIUM-INDIUM; PHASE-EQUILIBRIA; GOLD; COPPER; INTERMETALLICS; SYSTEMS; HEAT; TIN;
D O I
10.1016/j.molliq.2019.112439
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Thermodynamic properties of the liquid Au-Ga-In alloys have not been studied yet. Hence, the partial and integral mixing enthalpies of liquid phase in the Au-Ga-In ternary system were determined by applying drop calorimetry. Measurements were carried out at three temperatures: 1223 K, 1323 K and 1423 K, and along two cross-sections: X-Au/X-Ga = 1:1 and X-Ga/X-In = 1:1. The experimental data showed that the mixing enthalpy in this ternary system is not temperature dependent. The integral enthalpy of mixing for liquid Au-Ga-In phase was described by using the Redlich-Kister-Muggianu model for substitutional ternary solutions. (C) 2020 The Authors. Published by Elsevier B.V.
引用
收藏
页数:11
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