Guanidine-catalyzed Henry reaction and Knoevenagel condensation

被引:72
|
作者
Han, Junjie [1 ]
Xu, Yanfen [1 ]
Su, Yingpeng [1 ]
She, Xuegong [1 ]
Pan, Xinfu [1 ]
机构
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
基金
中国国家自然科学基金;
关键词
guanidine; organocatalyst; Henry reaction; Knoevenagel condensation;
D O I
10.1016/j.catcom.2008.04.006
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A method for direct Henry reaction and Knoevenagel condensation promoted by guanidine organocatalyst has been developed. The relationship of the structure and amount catalyst has been investigated. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:2077 / 2079
页数:3
相关论文
共 50 条
  • [1] ENANTIOMERICALLY PURE GUANIDINE-CATALYZED ASYMMETRIC NITROALDOL REACTION
    CHINCHILLA, R
    NAJERA, C
    SANCHEZAGULLO, P
    TETRAHEDRON-ASYMMETRY, 1994, 5 (07) : 1393 - 1402
  • [2] An Unexpected Guanidine-catalyzed Amination Reaction Leading to (Z)-α-Aminocinnamamides
    Bo Jiang
    Tu, Shu-Jiang
    CHEMISTRY LETTERS, 2010, 39 (03) : 210 - 211
  • [3] Highly Stereoselective Synthesis of Trisubstituted Cyclohexanols Using a Guanidine-Catalyzed Tandem Henry-Michael Reaction
    Dai, Qipu
    Huang, Huicai
    Zhao, John Cong-Gui
    JOURNAL OF ORGANIC CHEMISTRY, 2013, 78 (08): : 4153 - 4157
  • [4] Chiral Bifunctional Guanidine-Catalyzed Enantioselective Aza-Henry Reaction of Isatin-Derived Ketimines
    Fang, Bing
    Liu, Xiaohua
    Zhao, Jiannan
    Tang, Yu
    Lin, Lili
    Feng, Xiaoming
    JOURNAL OF ORGANIC CHEMISTRY, 2015, 80 (06): : 3332 - 3338
  • [5] Mechanistic considerations of guanidine-catalyzed reactions
    Fu, Xiao
    Tan, Choon-Hong
    CHEMICAL COMMUNICATIONS, 2011, 47 (29) : 8210 - 8222
  • [6] Density functional study on the mechanism of bicyclic guanidine-catalyzed Strecker reaction
    Li, J
    Jiang, WY
    Han, KL
    He, GZ
    Li, C
    JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (23): : 8786 - 8789
  • [7] Preparation of monoglycerides by guanidine-catalyzed processes
    Aguiar, LMG
    Vargas, RM
    JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1998, 75 (06) : 755 - 756
  • [8] Guanidine-catalyzed asymmetric Strecker reaction: modes of activation and origin of stereoselectivity
    Xue, Hansong
    Tan, Choon-Hong
    Wong, Ming Wah
    CANADIAN JOURNAL OF CHEMISTRY, 2016, 94 (12) : 1099 - 1108
  • [9] Rate Acceleration of Triethylamine-Mediated Guanidine-Catalyzed Enantioselective Michael Reaction
    Jiang, Zhiyong
    Ye, Weiping
    Yang, Yuanyong
    Tan, Choon-Hong
    ADVANCED SYNTHESIS & CATALYSIS, 2008, 350 (14-15) : 2345 - 2351
  • [10] Copper/Guanidine-Catalyzed Asymmetric Alkynylation of Isatins
    Chen, Quangang
    Tang, Yu
    Huang, Tianyu
    Liu, Xiaohua
    Lin, Lili
    Feng, Xiaoming
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (17) : 5286 - 5289