CO oxidation from syngas (CO and H2) using nanoporous Pt/Al2O3 catalyst

被引:4
|
作者
Bae, Jong-Soo [1 ]
Park, Joo-Won [1 ]
Kim, Jae-Ho [2 ]
Lee, Jae-Goo [2 ]
Kim, Younghun [1 ]
Han, Choon [1 ]
机构
[1] Kwangwoon Univ, Dept Chem Engn, Seoul 139701, South Korea
[2] Korea Inst Energy Res, Gasificat Res Ctr, Taejon 305343, South Korea
关键词
CO Oxidation; Pt/Al2O3; Nanoporous Alumina; Hydrogen Energy; CH4;
D O I
10.1007/s11814-010-0248-x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The concept of "waste-to-wealth" is spreading awareness to prevent global warming and recycle the restrictive resources. To contribute towards sustainable development, hydrogen energy is obtained from syngas (CO and H-2) generated from waste gasification, followed by CO oxidation and CO2 removal. in H-2 generation, it is key to produce more purified H-2 from syngas using heterogeneous catalysts. In this respect, we prepared Pt/Al2O3 catalyst with nanoporous structure using precipitation method, and compared its catalytic activity with commercial alumina (Degussa). Based on the results of XRD and TEM, it was found that metal particles did not aggregate on the alumina surface and showed high dispersion. Optimum condition for CO conversion was 1.5 wt% Pt loaded on Al2O3 support, and pure hydrogen was obtained after removal of CO2 gas.
引用
收藏
页码:1458 / 1461
页数:4
相关论文
共 50 条
  • [21] Preferential CO oxidation over Pt–SnO2/Al2O3 in hydrogen rich streams containing CO2 and H2O (CO removal from H2 with PROX)
    Gökhan Uysal
    A. Nilgün Akın
    Z. İlsen Önsan
    Ramazan Yıldırım
    Catalysis Letters, 2006, 111 : 173 - 176
  • [22] Preferential CO oxidation over Pt-SnO2/Al2O3 in hydrogen rich streams containing CO2 and H2O (CO removal from H2 with PROX)
    Uysal, Gokhan
    Akin, A. Nilgun
    Onsan, Z. Ilsen
    Yildirim, Ramazan
    CATALYSIS LETTERS, 2006, 111 (3-4) : 173 - 176
  • [23] CO/H2 adsorption and reaction on a reduced Mo/-Al2O3 catalyst.
    Kong, X
    Liu, D
    Wang, ZX
    Que, GH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 226 : U261 - U261
  • [24] A highly active Pt-Fe/γ-Al2O3 catalyst for preferential oxidation of CO in excess of H2 with a wide operation temperature window
    Lou, Yang
    Liu, Jingyue
    CHEMICAL COMMUNICATIONS, 2017, 53 (64) : 9020 - 9023
  • [25] DME Synthesis From CO/H2 over Cu-Mn/Ă-Al2O3 Catalyst
    Gong-Xin Qi
    Jin-Hua Fei
    Xiao-Ming Zheng
    Zhao-Yin Hou
    Reaction Kinetics and Catalysis Letters, 2001, 73 : 245 - 256
  • [26] DME synthesis from CO/H2 over Cu-Mn/γ-Al2O3 catalyst
    Qi, GX
    Fei, JH
    Zheng, XM
    Hou, ZY
    REACTION KINETICS AND CATALYSIS LETTERS, 2001, 73 (02): : 245 - 256
  • [27] Understanding the role of K on PtCo/Al2O3 for preferential oxidation of CO in H2
    Lou, Yake
    Zhong, Liding
    Zhang, Cheng
    Guo, Yanglong
    Zhan, Wangcheng
    Guo, Yun
    Wang, Li
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2022, 47 (76) : 32503 - 32515
  • [28] Fischer-Tropsch synthesis on a Co/Al2O3 catalyst with CO2 containing syngas
    Visconti, Carlo Giorgio
    Lietti, Luca
    Tronconi, Enrico
    Forzatti, Pio
    Zennaro, Roberto
    Finocchio, Elisabetta
    APPLIED CATALYSIS A-GENERAL, 2009, 355 (1-2) : 61 - 68
  • [29] Heats of adsorption using temperature programmed adsorption equilibrium:: Application to the adsorption of CO on Cu/Al2O3 and H2 on Pt/Al2O3
    Derrouiche, S
    Bianchi, D
    LANGMUIR, 2004, 20 (11) : 4489 - 4497
  • [30] SPILLOVER OF CO AND H2 ONTO AL2O3 SURFACES
    SEN, B
    FALCONER, JL
    MAO, TF
    YU, M
    FLESNER, RL
    JOURNAL OF CATALYSIS, 1990, 126 (02) : 465 - 476