CO oxidation from syngas (CO and H2) using nanoporous Pt/Al2O3 catalyst

被引:4
|
作者
Bae, Jong-Soo [1 ]
Park, Joo-Won [1 ]
Kim, Jae-Ho [2 ]
Lee, Jae-Goo [2 ]
Kim, Younghun [1 ]
Han, Choon [1 ]
机构
[1] Kwangwoon Univ, Dept Chem Engn, Seoul 139701, South Korea
[2] Korea Inst Energy Res, Gasificat Res Ctr, Taejon 305343, South Korea
关键词
CO Oxidation; Pt/Al2O3; Nanoporous Alumina; Hydrogen Energy; CH4;
D O I
10.1007/s11814-010-0248-x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The concept of "waste-to-wealth" is spreading awareness to prevent global warming and recycle the restrictive resources. To contribute towards sustainable development, hydrogen energy is obtained from syngas (CO and H-2) generated from waste gasification, followed by CO oxidation and CO2 removal. in H-2 generation, it is key to produce more purified H-2 from syngas using heterogeneous catalysts. In this respect, we prepared Pt/Al2O3 catalyst with nanoporous structure using precipitation method, and compared its catalytic activity with commercial alumina (Degussa). Based on the results of XRD and TEM, it was found that metal particles did not aggregate on the alumina surface and showed high dispersion. Optimum condition for CO conversion was 1.5 wt% Pt loaded on Al2O3 support, and pure hydrogen was obtained after removal of CO2 gas.
引用
收藏
页码:1458 / 1461
页数:4
相关论文
共 50 条
  • [1] CO oxidation from syngas (CO and H2) using nanoporous Pt/Al2O3 catalyst
    Jong-Soo Bae
    Joo-Won Park
    Jae-Ho Kim
    Jae-Goo Lee
    Younghun Kim
    Choon Han
    Korean Journal of Chemical Engineering, 2010, 27 : 1458 - 1461
  • [2] Promotion of Pt/γ-Al2O3 by Ce for preferential oxidation of CO in H2
    Son, IH
    Lane, AM
    CATALYSIS LETTERS, 2001, 76 (3-4) : 151 - 154
  • [3] Promotion of Pt/γ-Al2O3 by Ce for Preferential Oxidation of CO in H2
    In Hyuk Son
    Alan M. Lane
    Catalysis Letters, 2001, 76 : 151 - 154
  • [4] Removal of CO2 from Syngas(CO2 and H-2) Using Nanoporous Na2CO3/ Al2O3 Adsorbents
    Bae, Jong-Soo
    Park, Joo-Won
    Kim, Jae-Ho
    Lee, Jae-Goo
    Kim, Younghun
    Han, Choon
    KOREAN CHEMICAL ENGINEERING RESEARCH, 2009, 47 (05): : 646 - 650
  • [5] Reduction of stored NOx on Pt/Al2O3 and Pt/BaO/Al2O3 catalysts with H2 and CO
    Szailer, T
    Kwak, JH
    Kim, DH
    Hanson, JC
    Peden, CHF
    Szanyi, J
    JOURNAL OF CATALYSIS, 2006, 239 (01) : 51 - 64
  • [6] In situ FT-IR study of CO and H2 adsorption on a Pt/Al2O3 catalyst
    Liu, D
    Que, GH
    Wang, ZX
    Yan, ZF
    CATALYSIS TODAY, 2001, 68 (1-3) : 155 - 160
  • [7] Effect of phase composition between nano γ- and χ-Al2O3 on Pt/Al2O3 catalyst in CO oxidation
    Vleephoka, Chatchai
    Chaisuk, Choowong
    Samparnpiboon, Panida
    Praserthdam, Piyasan
    CATALYSIS COMMUNICATIONS, 2008, 9 (04) : 546 - 550
  • [8] Preferential CO oxidation promoted by the presence of H2 over K-Pt/Al2O3
    Minemura, Y
    Ito, S
    Miyao, T
    Naito, S
    Tomishige, K
    Kunimori, K
    CHEMICAL COMMUNICATIONS, 2005, (11) : 1429 - 1431
  • [9] Local structure of Pt species dictates remarkable performance on Pt/Al2O3 for preferential oxidation of CO in H2
    Chen, Yang
    Lin, Jian
    Li, Lin
    Pan, Xiaoli
    Wang, Xiaodong
    Zhang, Tao
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2021, 282
  • [10] Pt–Ni/γ-Al2O3 catalyst for the preferential CO oxidation in the hydrogen stream
    Eun-Yong Ko
    Eun Duck Park
    Kyung Won Seo
    Hyun Chul Lee
    Doohwan Lee
    Soonho Kim
    Catalysis Letters, 2006, 110 : 275 - 279