Design of magnesium phosphate cement based composite for high performance bipolar plate of fuel cells

被引:12
|
作者
Hao, Wenbin [1 ]
Ma, Hongyan [1 ,2 ]
Lu, Zeyu [1 ]
Sun, Guoxing [1 ]
Li, Zongjin [1 ]
机构
[1] Hong Kong Univ Sci & Technol, Dept Civil & Environm Engn, Kowloon, Hong Kong, Peoples R China
[2] Missouri Univ Sci & Technol, Dept Civil Architectural & Environm Engn, Rolla, MO 65401 USA
关键词
PORE STRUCTURE;
D O I
10.1039/c6ra11573j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this work, we report a comprehensive study on a magnesium phosphate cement (MPC) based composite as the construction material for high performance bipolar plates of fuel cells. MPC with partial replacement of fly ash was employed as the binding matrix. Some carbon-based materials, such as graphite, carbon black, carbon fiber, and multi-walled carbon nanotubes were used to construct the conductive phase. A simple hot-press process was applied to produce the composite. The formula and the structure of the composite was modified and adjusted to optimize the properties of the composite to meet the US DOE 2015 technical targets, including the introducing of a reinforcement support. Finally, all the technical targets such as electrical conductivity (>100 S cm(-1)), the flexural strength (>25 MPa), the corrosion resistance (<1 mu A cm(-2)), and gas permeability (<10(-5) cm(3) ( s cm(2))(-1)) were achieved as well as low cost (<5 $ per kW). The optimized formula and the detailed procedures to fabricate the MPC based composite were concluded.
引用
收藏
页码:56711 / 56720
页数:10
相关论文
共 50 条
  • [31] Integrated carbon composite bipolar plate for polymer-electrolyte membrane fuel cells
    Yu, Ha Na
    Hwang, In Uk
    Kim, Seong Su
    Lee, Dai Gil
    JOURNAL OF POWER SOURCES, 2009, 189 (02) : 929 - 934
  • [32] Prospects of graphite - polypropylene/epoxy blend composite for high performance bipolar plate in polymer electrolyte membrane fuel cell
    Alo, O. A.
    Otunniyi, I. O.
    Pienaar, H. C. V. Z.
    CONFERENCE OF THE SOUTH AFRICAN ADVANCED MATERIALS INITIATIVE (COSAAMI 2019), 2019, 655
  • [33] Effect of phosphate-to-magnesium ratio on the performance of magnesium potassium phosphate cement-based steel fireproof coatings
    Hu, Cheng
    Lin, Xujian
    Shao, Xiaoyan
    Ji, Tao
    Lin, Huangqi
    Huang, Wuyan
    Xu, Yihui
    JOURNAL OF THE CHINESE INSTITUTE OF ENGINEERS, 2025, 48 (02) : 195 - 203
  • [34] Fabrication of high strength and a low weight composite bipolar plate for fuel cell applications
    Maheshwari, Priyanka H.
    Mathur, R. B.
    Dhami, T. L.
    JOURNAL OF POWER SOURCES, 2007, 173 (01) : 394 - 403
  • [35] Magnesium phosphate cement-based engineered cementitious composites with polyethylene fibers: Performance improvement and design method
    Nie, Shuang
    Guo, Aofei
    Feng, Hu
    Yu, Zhenyun
    Hu, Qunfang
    JOURNAL OF CLEANER PRODUCTION, 2024, 450
  • [36] High performance polymeric bipolar plate based on polypropylene/graphite/graphene/nano-carbon black composites for PEM fuel cells
    Adloo, Ali
    Sadeghi, Morteza
    Masoomi, Mahmood
    Pazhooh, Hadi Najafi
    RENEWABLE ENERGY, 2016, 99 : 867 - 874
  • [37] Bioactive tetracalcium phosphate/magnesium phosphate composite bone cement for bone repair
    Liu, Jingxian
    Liao, Jianguo
    Li, Yanqun
    Yang, Zhengpeng
    Ying, Qiwei
    Xie, Yufen
    Zhou, Aiguo
    JOURNAL OF BIOMATERIALS APPLICATIONS, 2019, 34 (02) : 239 - 249
  • [38] Synthesis and Characterization of New Composite Materials Based on Magnesium Phosphate Cement for Fluoride Retention
    Gharsallah, Sana
    Alsawi, Abdulrahman
    Hammami, Bechir
    Khitouni, Mohamed
    Charnay, Clarence
    Chemingui, Mahmoud
    MATERIALS, 2023, 16 (02)
  • [39] Carbon composite bipolar plate for high-temperature proton exchange membrane fuel cells (HT-PEMFCs)
    Lee, Dongyoung
    Lee, Dai Gil
    JOURNAL OF POWER SOURCES, 2016, 327 : 119 - 126
  • [40] Reaction mechanism of magnesium potassium phosphate cement with high magnesium-to-phosphate ratiod
    Xu, Biwan
    Lothenbach, Barbara
    Leemann, Andreas
    Winnefeld, Frank
    CEMENT AND CONCRETE RESEARCH, 2018, 108 : 140 - 151