Design of magnesium phosphate cement based composite for high performance bipolar plate of fuel cells

被引:12
|
作者
Hao, Wenbin [1 ]
Ma, Hongyan [1 ,2 ]
Lu, Zeyu [1 ]
Sun, Guoxing [1 ]
Li, Zongjin [1 ]
机构
[1] Hong Kong Univ Sci & Technol, Dept Civil & Environm Engn, Kowloon, Hong Kong, Peoples R China
[2] Missouri Univ Sci & Technol, Dept Civil Architectural & Environm Engn, Rolla, MO 65401 USA
关键词
PORE STRUCTURE;
D O I
10.1039/c6ra11573j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this work, we report a comprehensive study on a magnesium phosphate cement (MPC) based composite as the construction material for high performance bipolar plates of fuel cells. MPC with partial replacement of fly ash was employed as the binding matrix. Some carbon-based materials, such as graphite, carbon black, carbon fiber, and multi-walled carbon nanotubes were used to construct the conductive phase. A simple hot-press process was applied to produce the composite. The formula and the structure of the composite was modified and adjusted to optimize the properties of the composite to meet the US DOE 2015 technical targets, including the introducing of a reinforcement support. Finally, all the technical targets such as electrical conductivity (>100 S cm(-1)), the flexural strength (>25 MPa), the corrosion resistance (<1 mu A cm(-2)), and gas permeability (<10(-5) cm(3) ( s cm(2))(-1)) were achieved as well as low cost (<5 $ per kW). The optimized formula and the detailed procedures to fabricate the MPC based composite were concluded.
引用
收藏
页码:56711 / 56720
页数:10
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