Synthesis of a new polymer containing Rose Bengal

被引:3
|
作者
Saánchez, EI [1 ]
Calderón, M [1 ]
Gutiérrez, MI [1 ]
机构
[1] Univ Nacl Patagonia San Juan Bosco, Fac Ciencias Nat, RA-9000 Comodoro Rivadavia, Argentina
关键词
D O I
10.1007/s00289-003-0222-4
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Rose Bengal (4,5,6,7-tetrachloro-2',4',5',7'-tetraiodofluorescein, RB), a xanthene dye well-known as singlet molecular oxygen photosensitizer, was bound to the polymeric matrix poly(butadiene-hydroxyethylmethacrylate-epichlorhydrin) (PB-HEMA-ECH). The new polymer-bound dye (P-RB) was investigated as sensitizer for the photooxidation in air equilibrated solutions of model compounds (Q). Comparative results of degradation of these compounds suggest the generation of singlet oxygen. Also P-RB showed good stability and was reused.
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页码:271 / 275
页数:5
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