Highly enantioselective spiro cyclization of 1,6-enynes catalyzed by cationic skewphos rhodium(I) complex

被引：39
|
作者：
Mikami, K [1 ]
Yusa, Y [1 ]
Hatano, M [1 ]
Wakabayashi, K [1 ]
Aikawa, K [1 ]
机构：
[1] Tokyo Inst Technol, Dept Appl Chem, Tokyo 1528552, Japan
来源：
CHEMICAL COMMUNICATIONS | 2004年 / 01期
关键词：
D O I：
10.1039/b310789b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A cationic rhodium(I) complex having a skewphos ligand is shown to be a highly enantioselective catalyst for asymmetric carbocyclization of 1,6-enynes with tri-substituted olefins to control quaternary stereogenic centers of spiro-rings.
引用
收藏
页码：98 / 99
页数：2
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