Gas Diffusion in Fractal Porous Media

被引:40
|
作者
Cao, Liyong [1 ]
He, Rong [1 ]
机构
[1] Tsinghua Univ, Dept Thermal Engn, Beijing 10084, Peoples R China
基金
中国国家自然科学基金;
关键词
Char pores; Diffusion; Fractal; TEMPERATURE COMBUSTION-RATE; COAL CHAR; COMPUTER-SIMULATION; ANOMALOUS DIFFUSION; OXIDATION BEHAVIOR; PORES; DIMENSIONS; EVOLUTION; CLUSTERS;
D O I
10.1080/00102200903341553
中图分类号
O414.1 [热力学];
学科分类号
摘要
Gas diffusion in char pores or other fractal pores is anomalous diffusion that does not follow Fick's diffusion law. The authors studied gas diffusion in fractal porous media by simulating molecular movements in porous models. Through analyzing numerical results, gas diffusion equations in fractal pores have been presented. The effects of geometrical structures on pore diffusion can be described by three parameters: porosity, specific surface area, and fractal dimension. With these three parameters, the diffusion coefficient can be calculated. The steady-state diffusion equation is quantitatively determined so that it can be potentially used in modeling char combustion or other practical applications.
引用
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页码:822 / 841
页数:20
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