Detection of Lead Ions with Fe3O4/Ag Core-Shell Nanoparticles

被引:6
|
作者
Jiang, Caiyun [1 ]
Ma, Xiaoyuan [3 ]
Yu, Fang [1 ]
Shi, Xueping [1 ]
Yang, Aiping [1 ]
Wang, Yuping [2 ]
机构
[1] Jiangsu Inst Commerce, Jiangsu Engn & Res Ctr Food Safety, Dept Engn & Technol, Nanjing 210007, Jiangsu, Peoples R China
[2] Nanjing Normal Univ, Coll Chem & Mat Sci, Nanjing 210097, Jiangsu, Peoples R China
[3] Jiangnan Univ, Sch Food Sci & Technol, Wuxi 214122, Peoples R China
基金
中国国家自然科学基金;
关键词
Fe3O4; Ag; Core-Shell Nanoparticles; Pb2+; Coordination; MAGNETIC NANOPARTICLES; WASTE-WATER; METAL-IONS; PB(II); RISK; PRECONCENTRATION; ADSORPTION; COMPLEXES; TOXICITY; INDUSTRY;
D O I
10.1166/jnn.2016.11345
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fe3O4/Ag core-shell nanoparticles were used for the detection of Pb2+. Using the Fe3O4 magnetic nanoparticles with small size, the Fe3O4/Ag core-shell nanoparticles were synthesized by reducing Ag[(NH3)(2)](+) with gallic acid (GA) as a reducer and surface modifier. With the help of the coordination behavior of Pb2+ with the GA molecules bonded on the surface of the core-shell nanoparticles, it can be performed to quantitatively detect the Pb2+. The linear response range is from 5 x 10(-9) M to 1.0 x 10(-5) M. The developed method shows a good selectivity for Pb2+. The Fe3O4/Ag core-shell nanoparticles are easily to recover for their magnetism. After being treated with EDTA, the Fe3O4/Ag core-shell nanoparticles can be used again and, therefore, the testing costs can be reduced.
引用
收藏
页码:7215 / 7219
页数:5
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