Degradation of phenylmercury compounds by heterogeneous photocatalysis over α-Fe2O3

被引：0
|
作者：
Navio, J. A. [1 ,2 ]
Cerrillos, C.
Macias, M. [1 ,2 ]
Pradera, M. A. [3 ]
机构：
[1] Univ Seville, Ctr Mixto CSIC, Inst Ciencia Mat Sevilla, Seville 41092, Spain
[2] Univ Seville, Dpto Quim Inorgan, Seville 41092, Spain
[3] Univ Seville, Fac Quim, Dpto Quim Organ, Seville 41012, Spain
来源：
JOURNAL OF ADVANCED OXIDATION TECHNOLOGIES | 2008年 / 11卷 / 02期
关键词：
mercury; phenylmercury compounds; heterogeneous photocatalysis; alpha-Fe2O3;
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We report here on the degradation of diphenylmercury and monophenylmercury chloride in air-equilibrated aqueous solutions by heterogeneous photocatalysis over alpha-Fe2O3. Photocatalysis proceeded via sequential de-phenylation leaving inorganic mercury. GC-MS analysis of the products revealed that photocatalytic degradation involved hydroxylation of the phenyl rings. Mechanistic features and photocatalytic activity were also studied and are reported upon.
引用
收藏
页码：411 / 416
页数：6
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