'Illusional' nano-size effect due to artifacts of in-plane conductivity measurements of ultra-thin films

被引:36
|
作者
Kim, Hae-Ryoung [1 ]
Kim, Jong-Cheol [1 ]
Lee, Kyung-Ryul [1 ]
Ji, Ho-Il [1 ]
Lee, Hae-Weon [1 ]
Lee, Jong-Ho [1 ]
Son, Ji-Won [1 ]
机构
[1] Korea Inst Sci & Technol, High Temp Energy Mat Ctr, Seoul 136791, South Korea
关键词
PULSED-LASER DEPOSITION; OXIDE FUEL-CELLS; ELECTRICAL-CONDUCTIVITY; IONIC-CONDUCTIVITY; NANOCRYSTALLINE CERIA; HETEROSTRUCTURES; SUPERLATTICES; ENERGY;
D O I
10.1039/c0cp02673e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The nano-size effect, which indicates a drastic increase in conductivity in solid electrolyte materials of nano-scale microstructures, has drawn substantial attention in various research fields including in the field of solid oxide fuel cells (SOFCs). However, especially in the cases of the conductivity of ultra-thin films measured in an in-plane configuration, it is highly possible that the 'apparent' conductivity increase originates from electrical current flowing through other conduction paths than the thin film. As a systematic study to interrogate those measurement artifacts, we report various sources of electrical current leaks regarding in-plane conductivity measurements, specifically insulators in the measurement set-up. We have observed a 'great conductivity increase' up to an order of magnitude at a very thin thickness of a single layer yttria-stabilized zirconia (YSZ) film in a set-up with an intentional artifact current flow source. Here we propose that the nano-size effect, reported to appear in ultra-thin single layer YSZ, can be a result of misinterpretation.
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页码:6133 / 6137
页数:5
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