共 31 条
'Illusional' nano-size effect due to artifacts of in-plane conductivity measurements of ultra-thin films
被引:36
|作者:
Kim, Hae-Ryoung
[1
]
Kim, Jong-Cheol
[1
]
Lee, Kyung-Ryul
[1
]
Ji, Ho-Il
[1
]
Lee, Hae-Weon
[1
]
Lee, Jong-Ho
[1
]
Son, Ji-Won
[1
]
机构:
[1] Korea Inst Sci & Technol, High Temp Energy Mat Ctr, Seoul 136791, South Korea
关键词:
PULSED-LASER DEPOSITION;
OXIDE FUEL-CELLS;
ELECTRICAL-CONDUCTIVITY;
IONIC-CONDUCTIVITY;
NANOCRYSTALLINE CERIA;
HETEROSTRUCTURES;
SUPERLATTICES;
ENERGY;
D O I:
10.1039/c0cp02673e
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
The nano-size effect, which indicates a drastic increase in conductivity in solid electrolyte materials of nano-scale microstructures, has drawn substantial attention in various research fields including in the field of solid oxide fuel cells (SOFCs). However, especially in the cases of the conductivity of ultra-thin films measured in an in-plane configuration, it is highly possible that the 'apparent' conductivity increase originates from electrical current flowing through other conduction paths than the thin film. As a systematic study to interrogate those measurement artifacts, we report various sources of electrical current leaks regarding in-plane conductivity measurements, specifically insulators in the measurement set-up. We have observed a 'great conductivity increase' up to an order of magnitude at a very thin thickness of a single layer yttria-stabilized zirconia (YSZ) film in a set-up with an intentional artifact current flow source. Here we propose that the nano-size effect, reported to appear in ultra-thin single layer YSZ, can be a result of misinterpretation.
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页码:6133 / 6137
页数:5
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