Bimetallic Zn and Hf on Silica Catalysts for the Conversion of Ethanol to 1,3-Butadiene

被引：72

作者：

De Baerdemaeker, Trees ^{[1
]}

Feyen, Mathias ^{[2
]}

Mueller, Ulrich ^{[2
]}

Yilmaz, Bilge ^{[3
]}

Xiao, Feng-Shou ^{[4
]}

Zhang, Weiping ^{[5
]}

Yokoi, Toshiyuki ^{[6
]}

Bao, Xinhe ^{[7
]}

Gies, Hermann ^{[8
]}

De Vos, Dirk E. ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Leuven, Belgium

[2] BASF SE, Proc Res & Chem Engn, D-67056 Ludwigshafen, Germany

[3] BASF Corp, Proc Catalysts & Technol, Iselin, NJ 08830 USA

[4] Zhejiang Univ, Hangzhou 310028, Zhejiang, Peoples R China

[5] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China

[6] Tokyo Inst Technol, Chem Resources Lab, Yokohama, Kanagawa 2268503, Japan

[7] Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

[8] Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44780 Bochum, Germany

来源：

ACS CATALYSIS | 2015年 / 5卷 / 06期

关键词：

1,3-butadiene; ethanol; zinc silicate; hemimorphite; heterogeneous catalysis; silica impregnation; MAGNESIUM-OXIDE; METAL-OXIDES; BUTADIENE; HYDROXYAPATITE; TRANSFORMATION; SELECTIVITY; BASICITY; ACETONE; LEBEDEV;

D O I：

10.1021/acscatal.5b00376

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Silica-supported catalysts for the conversion of ethanol to 1,3-butadiene were investigated. The combination of Hf(IV) and Zn(II) resulted in a stable, active, and selective catalyst in which the Zn(II) effectively suppressed the dehydration activity of Hf(IV); the catalyst preparation method plays a crucial role. Using the crystalline Zn-silicate hemimorphite as an alternative Zn(II) source proved to be even more successful in suppressing ethanol dehydration.

引用

页码：3393 / 3397

页数：5

共 50 条

[31] Catalytic Activity of Bimetallic Cu-Ag/MgO-SiO2 Toward the Conversion of Ethanol to 1,3-Butadiene
Tripathi, Anamol
Faungnawakij, Kajornsak
Laobuthee, Apirat
Assabumrungrat, Suttichai
Laosiripojna, Navadol
INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING, 2016, 14 (05) : 945 - 954
[32] Effect of Lanthanum in Zn-La(-Zr)-Si Oxide Compositions on their Activity in the Conversion of Ethanol into 1,3-Butadiene
Larina, O. V.
Kyriienko, P. I.
Soloviev, S. O.
THEORETICAL AND EXPERIMENTAL CHEMISTRY, 2016, 52 (01) : 51 - 56
[33] Morphological control of inverted MgO-SiO2 composite catalysts for efficient conversion of ethanol to 1,3-butadiene
Li, Shenxiao
Men, Yong
Wang, Jinguo
Liu, Shuang
Wang, Xuefei
Ji, Fei
Chai, Shanshan
Song, Qiaoling
APPLIED CATALYSIS A-GENERAL, 2019, 577 : 1 - 9
[34] CATALYTIC CONVERSION OF ETHANOL INTO 1,3-BUTADIENE OVER ZNO-SUPPORTED SEPIOLITE
KITAYAMA, Y
ABE, A
NIPPON KAGAKU KAISHI, 1989, (11) : 1824 - 1829
[35] Modelling the effects of reaction temperature and flow rate on the conversion of ethanol to 1,3-butadiene
Da Ros, Simoni
Jones, Matthew D.
Mattia, Davide
Schwaab, Marcio
Noronha, Fabio B.
Pinto, Jose Carlos
APPLIED CATALYSIS A-GENERAL, 2017, 530 : 37 - 47
[36] Influence of structural parameters on the conversion of ethanol into 1,3-butadiene using mesoporous zeolites
Klein, Alexander
Palkovits, Regina
CATALYSIS COMMUNICATIONS, 2017, 91 : 72 - 75
[37] Pd-Au bimetallic catalysts supported on ZnO for selective 1,3-butadiene hydrogenation
Bachiller-Baeza, Belen
Iglesias-Juez, Ana
Agostini, Giovanni
Castillejos-Lopez, Eva
CATALYSIS SCIENCE & TECHNOLOGY, 2020, 10 (08) : 2503 - 2512
[38] Effect of oxide supports on Pd-Ni bimetallic catalysts for 1,3-butadiene hydrogenation
Hou, Ruijun
Porosoff, Marc D.
Chen, Jingguang G.
Wang, Tiefeng
APPLIED CATALYSIS A-GENERAL, 2015, 490 : 17 - 23
[39] VARIETIES OF MGO CATALYSTS FOR 1,3-BUTADIENE HYDROGENATION
MIYAHARA, K
MURATA, Y
TOYOSHIMA, I
TANAKA, Y
YOKOYAMA, T
JOURNAL OF CATALYSIS, 1981, 68 (01) : 186 - 189
[40] VAPOR-PHASE CATALYTIC CONVERSION OF ETHANOL INTO 1,3-BUTADIENE ON Cr-Ba/MCM-41 CATALYSTS
La-Salvia, N.
Lovon-Quintana, J. J.
Valenca, G. P.
BRAZILIAN JOURNAL OF CHEMICAL ENGINEERING, 2015, 32 (02) : 489 - 500

← 1 2 3 4 5 →