Electrochemical and photocatalytic hydrogen evolution by an electron-deficient cobalt tris(ethoxycarbonyl)corrole complex

被引：24

作者：

Yuan, Hui-Qing ^{[1
]}

Wang, Hua-Hua ^{[1
]}

Kandhadi, Jaipal ^{[2
]}

Wang, Hui ^{[2
]}

Zhan, Shu-Zhong ^{[1
]}

Liu, Hai-Yang ^{[1
]}

机构：

[1] South China Univ Technol, Dept Chem, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China

[2] Sun Yat Sen Univ, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Guangdong, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2017年 / 31卷 / 11期

基金：

中国国家自然科学基金;

关键词：

cobalt; corrole; electrocatalyst; hydrogen evolution; photocatalyst; MOLYBDENUM-OXO CATALYST; MOLECULAR ELECTROCATALYSTS; HETEROGENEOUS CATALYSIS; GENERATING HYDROGEN; LOW OVERPOTENTIALS; CORROLE CATALYST; H-2; PRODUCTION; WATER; REACTIVITY; COBALOXIME;

D O I：

10.1002/aoc.3773

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

An electron-deficient flat 5,10,15-tris(ethoxycarbonyl)corrole (TECC) cobalt complex, [Co(TECC)(Py)(2)] (1; py = pyridine), was prepared and employed as a catalyst for homogeneous hydrogen evolution. It turns out that water can be successfully used as a proton source in acetonitrilewater (2:3 v/v) solvent system for electrocatalytic hydrogen evolution. Complex 1 is also an efficient photocatalyst for hydrogen generation from aqueous solution, an example of the first application of metal corrole as photocatalyst for hydrogen production.

引用

页数：9

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