An efficient high-yield synthesis for perfluorinated tertiary alkyl amines

被引：3

作者：

Felling, KW ^{[1
]}

Lagow, RJ ^{[1
]}

机构：

[1] Univ Texas, Coll Nat Sci, Dept Chem & Biochem, Austin, TX 78712 USA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2003年 / 123卷 / 02期

关键词：

direct fluorination; perfluorinated amines; perfluorotriethylamine; perfluorotri-n-propylamine; perfluorotri-n-butylamine; perfluorotri-n-pentylamine; perfluoro-N; N; '-tetramethylethylenediamine;

D O I：

10.1016/S0022-1139(03)00146-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We wish to report a high-yield synthesis of perfluorinated tertiary amines from their hydrocarbon analogues by direct fluorination. Yields up to 70%, with high purities, have been obtained from certain tertiary amines. This technique will likely develop into a new general method for producing perfluorinated amines. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：233 / 236

页数：4

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