Self-assembly and nanostructure formation of multi-functional organic π-donors

被引:54
|
作者
Iyoda, Masahiko [1 ]
Hasegawa, Masashi [1 ]
Enozawa, Hideo [1 ]
机构
[1] Tokyo Metropolitan Univ, Grad Sch Sci & Engn, Dept Chem, Tokyo, Japan
关键词
ELECTRON-TRANSFER OXIDATION; SHAPE-PERSISTENT; TETRATHIAFULVALENE DERIVATIVES; SUPRAMOLECULAR CHEMISTRY; RADICAL-CATIONS; BUILDING-BLOCKS; CHARGE-TRANSFER; HYDROGEN-BONDS; MIXED-VALENCE; MACROCYCLES;
D O I
10.1246/cl.2007.1402
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Self-assembly of tetrathiafulvalenes, their conjugated oligomers, and giant macrocyclic oligothiophenes in solution leads to important solvatochromic, thermochromic, electrochromic, and switching properties. Furthermore, based on the self-assembly in solution. various nanostructures can be constructed in the solid state to produce nanowires, nanoparticles, nanotubes, tapes, ribbons, and microcrystals. This article highlights the self-aggregation of organic pi-donors in solution and the formation of nanostructures from these pi-donors in the solid state.
引用
收藏
页码:1402 / 1407
页数:6
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