Silica supported Ru(salophen)Cl: An efficient and robust heterogeneous catalyst for epoxidation of alkenes with sodium periodate

被引：18
|
作者：
Hatefi, Mehdi [2 ]
Moghadam, Majid [1 ,3 ]
Mirkhani, Valiollah [1 ]
Sheikhshoaei, Iran [2 ]
机构：
[1] Univ Isfahan, Catalysis Div, Dept Chem, Esfahan 8174673441, Iran
[2] Shahid Bahonar Univ, Dept Chem, Kerman, Iran
[3] Univ Isfahan, Dept Nanotechnol Engn, Esfahan 8174673441, Iran
来源：
POLYHEDRON | 2010年 / 29卷 / 15期
关键词：
Silica; Ru(III) salophen; Alkene epoxidation; Periodate; Supported catalyst; ALKANE HYDROXYLATION CATALYST; POLYSTYRENE-BOUND IMIDAZOLE; ENANTIOSELECTIVE EPOXIDATION; SALEN COMPLEXES; AXIAL LIGAND; ASYMMETRIC EPOXIDATION; MN(SALEN) COMPLEXES; MN-SALEN; RUTHENIUM; MN(SALOPHEN)CL;
D O I：
10.1016/j.poly.2010.07.019
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In the present work, heterogenization of Ru(salophen)Cl via its axial ligation to silica-bound imidazole, Silm, is reported. The heterogeneous catalyst, [Ru(salophen)Cl-Silm], was characterized by elemental analysis, SEM, TEM, FT-IR and diffuse reflectance UV-Vis spectroscopic techniques. The catalyst, which is not soluble in water and common organic solvents, was used for efficient epoxidation of cyclic and linear alkenes with NaIO4 under agitation with magnetic stirring. This new heterogenized catalyst is of high stability and reusability in the oxidation reactions. The effect of reaction parameters such as solvent and oxidant in the epoxidation of cis-cyclooctene were also investigated. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2953 / 2958
页数：6
相关论文
共 50 条
  • [31] Silica-supported sodium carbonate: an efficient heterogeneous catalyst for the synthesis of new thiazolopyrimidine derivatives
    Gavhane, Priya D.
    Kadam, Shuddhodan N.
    Ambhore, Ajay N.
    Dawane, Bhaskar S.
    RESEARCH ON CHEMICAL INTERMEDIATES, 2021, 47 (10) : 3999 - 4011
  • [32] Efficient clay supported Pd nanoparticles as heterogeneous catalyst for arylation of alkenes
    Ghiaci, Mehran
    Ansari, Fatemeh
    Sadeghi, Zahra
    Gil, A.
    CATALYSIS COMMUNICATIONS, 2012, 21 : 82 - 85
  • [33] Graphene oxide nanosheet supported molybdenum complex: An efficient and recoverable catalyst for epoxidation of alkenes
    Zarnegaryan, Ali
    Kargar, Shiva
    APPLIED SURFACE SCIENCE ADVANCES, 2021, 4
  • [34] Epoxidation of alkenes by a highly reusable and efficient polymer-supported molybdenum carbonyl catalyst
    Grivani, G
    Tangestaninejad, S
    Habibi, MH
    Mirkhani, V
    CATALYSIS COMMUNICATIONS, 2005, 6 (06) : 375 - 378
  • [35] Efficient and reusable ruthenium salophen catalysts immobilized on carboxylated multi-walled carbon nanotubes for the epoxidation of hydrocarbons with sodium periodate
    Takbiri, Sam
    Zarea-Mehrjardi, Maedeh
    Moghadam, Majid
    Tangestanejad, Shahram
    Mirkhani, Valiollah
    Mohammadpoor-Baltork, Iraj
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2022, 19 (08) : 3597 - 3609
  • [36] Efficient and reusable ruthenium salophen catalysts immobilized on carboxylated multi-walled carbon nanotubes for the epoxidation of hydrocarbons with sodium periodate
    Sam Takbiri
    Maedeh Zarea-Mehrjardi
    Majid Moghadam
    Shahram Tangestanejad
    Valiollah Mirkhani
    Iraj Mohammadpoor-Baltork
    Journal of the Iranian Chemical Society, 2022, 19 : 3597 - 3609
  • [37] Host (nanocavity of zeolite-Y)-guest (manganese(III) salophen complex) nanocomposite materials: An efficient catalyst for biomimetic alkene epoxidation and alkane hydroxylation with sodium periodate
    Mirkhani, Valiollah
    Moghadam, Majid
    Tangestaninejad, Shahram
    Bahramian, Bahram
    Mallekpoor-Shalamzari, Akbar
    APPLIED CATALYSIS A-GENERAL, 2007, 321 (01) : 49 - 57
  • [38] A Recoverable Ruthenium Aqua Complex Supported on Silica Particles: An Efficient Epoxidation Catalyst
    Ferrer, Ingrid
    Fontrodona, Xavier
    Roig, Anna
    Rodriguez, Montserrat
    Romero, Isabel
    CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (17) : 4096 - 4107
  • [39] Manganese salophen covalently anchored to amino-functionalized graphene oxide as an efficient heterogeneous catalyst for selective epoxidation
    Hajian, Robabeh
    Mousavi, Narjes Sadat
    RSC ADVANCES, 2024, 14 (52) : 38470 - 38479
  • [40] Efficient synthesis of β-acetylamino ketones using silica-supported sodium hydrogen sulfate as a heterogeneous catalyst
    Kumari, N. Vijaya
    Nagarapu, Lingaiah
    Shivaraj
    SYNTHETIC COMMUNICATIONS, 2007, 37 (14) : 2325 - 2329
12345