Synthesis and characterization of substituted benzimidazole Co(II), Fe(II), and Zn(II) complexes and structural characterization of dichlorobis{1-[2-(1-piperidinyl)ethyl]-1H-benzimidazole-K N3} zinc(II)

被引：9
|
作者：
Kucukbay, Hasan [1 ]
Yilmaz, Ulku [2 ]
Akkurt, Mehmet [3 ]
Buyukgungor, Orhan [4 ]
机构：
[1] Inonu Univ, Fac Arts & Sci, Dept Chem, Malatya, Turkey
[2] Inonu Univ, Battalgazi Vocat Sch, Malatya, Turkey
[3] Erciyes Univ, Fac Sci, Dept Phys, Kayseri, Turkey
[4] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Phys, TR-55139 Kurupelit, Samsun, Turkey
来源：
TURKISH JOURNAL OF CHEMISTRY | 2015年 / 39卷 / 01期
关键词：
Benzimidazole metal complexes; transition metal complexes; coordination compounds; crystal structure; CROSS-COUPLING REACTIONS; CRYSTAL-STRUCTURE; METAL-COMPLEXES; ANTIMICROBIAL ACTIVITIES; CATALYTIC-ACTIVITY; ANTITUMOR-ACTIVITY; COBALT(II); LIGAND; COORDINATION; DERIVATIVES;
D O I：
10.3906/kim-1405-47
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Co(II), Fe(II), and Zn(II) complexes of 1-(3-phenyl)propylbenzimidazole (PPBI), 5-nitro-1-(3-phenyl) propylbenzimidazole (PPNBI), 1-[2-(4-morpholinyl)ethyl]benzimidazole (MEBI), 1-[2-(1-piperidinyl)ethyl]benzimidazole (PEBI), and 5-nitro-1-[2-(1-piperidinyl)ethyl]benzimidazole (PENBI) were synthesized and characterized by H-1 NMR, C-13 NMR, and elemental analyses. The magnitudes of the magnetic moments for paramagnetic complexes were between 4.07 and 5.11 B.M. Moreover, the crystal structure of dichlorobis{1-[2-(1-piperidinyl)ethyl]-1 H-benzimidazole-(K) N-3} zinc(II) was determined by single crystal X-ray diffraction.
引用
收藏
页码：108 / 120
页数：13
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