A high-performance dysprosium(III) single-ion magnet with quasi-Oh symmetry

被引：8
|
作者：
Lai, Jia-Jun [1 ]
Ruan, Ze-Yu [1 ]
Huang, Guo-Zhang [1 ]
Liu, Jun-Liang [1 ]
Tong, Ming-Liang [1 ]
机构：
[1] Sun Yat Sen Univ, Sch Chem, Minist Educ, Key Lab Bioinorgan & Synthet Chem, Guangzhou 510006, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2021年 / 132卷
关键词：
Single-ion Magnet; Octahedral Coordination Geometry; ZFC-FC measurements; ab initio calculations; MOLECULE MAGNET; MAGNETIZATION; ANISOTROPY; SHAPE; BARRIER; MAPS;
D O I：
10.1016/j.inoche.2021.108807
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A {Zn2Dy} single-ion magnet (SIM) with octahedral coordination geometry (O-h) was synthesized and characterized. The zero-field-cooled (ZFC) and field-cooled (FC) magnetic susceptibility measurement diverged below 4.1 K, revealing the presence of the magnetic blocking. Combining experimental data and ab initio calculations, we depicted the dynamic relaxation characters of this complex in detail.
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页数：5
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