Hydrothermal synthesis and structural characterization of an organic-inorganic hybrid material:: (H2tptz)2[δ-Mo8O26]•2H2O (tptz=2,4,6-tripyridyltriazine)

被引：64
|
作者：
Rarig, RS [1 ]
Zubieta, J [1 ]
机构：
[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA
来源：
INORGANICA CHIMICA ACTA | 2001年 / 312卷 / 1-2期
基金：
美国国家科学基金会;
关键词：
polyoxomolybdate cluster; hydrothermal synthesis; organic-inorganic hybrid material; delta-Mo8O264-;
D O I：
10.1016/S0020-1693(00)00332-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of MoO3 and 2,4,6-tripyridyltriazine (tptz) in water at 180 degreesC for 48h and pH 5.5 produces (H(2)tptz)(2)[Mo8O26]. 2H(2)O in 70% yield. The structure is constructed from delta -Mo8O264-. clusters, H(2)tptz(2+) and H3O+ cations linked through hydrogen bonding into a network. Crystal data: C18H16Mo4N6O14; monoclinic P2(1)/n; a = 10.2225(5) Angstrom, b = 14.0072(6) Angstrom, c = 18.1154(8) Angstrom, beta = 93.896(1)degrees, V = 2587.9(2) A(3), Z = 4, D-calc = 2.372 g cm(-3); R-1 = 0.0271 based on 3212 reflections. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：188 / 196
页数：9
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