Synthesis of new chiral catalysts, 2-azanorbornyloxazolidines, for enantioselective addition of diethylzinc to aldehydes

被引:0
|
作者
Nakano, H [1 ]
Okuyama, Y [1 ]
Iwasa, K [1 ]
Hongo, H [1 ]
机构
[1] Tohoku Pharmaceut Univ, Aoba Ku, Sendai, Miyagi 981, Japan
关键词
chiral oxazolidine; beta-amino alcohol; catalytic asymmetric synthesis; 2-azanorbornylmethanol; chiral secondary alcohol;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Optically active 2-azanorbornyloxazolidines were prepared from 2-azanorbornylmethanols and catalyzed the enantioselective addition of diethylzinc to aldehydes to give optically active secondary alcohols.
引用
收藏
页码:411 / 418
页数:8
相关论文
共 50 条
  • [31] Synthesis of Chiral Aminophenols Based on Proline and Their Application in Enantioselective Addition of Diethylzinc to Aldehydes
    葛健锋
    沈宗旋
    张雅文
    陆新华
    陆忠娥
    Chinese Journal of Chemistry, 2003, (07) : 950 - 954
  • [32] Synthesis and application of chiral β-amino disulfides as ligands for the enantioselective addition of diethylzinc to aldehydes
    Braga, Antonio L.
    Galetto, Fabio Z.
    Rodrigues, Oscar E. D.
    Silveira, Claudio C.
    Paixao, Marcio W.
    CHIRALITY, 2008, 20 (07) : 839 - 845
  • [33] Synthesis of chiral aminophenols based on proline and their application in enantioselective addition of diethylzinc to aldehydes
    Ge, JF
    Shen, ZX
    Zhang, YW
    Lu, XH
    Lu, ZE
    CHINESE JOURNAL OF CHEMISTRY, 2003, 21 (07) : 950 - 954
  • [35] C-2-symmetric chiral zinc alkoxides as catalysts for the enantioselective addition of diethylzinc to aryl aldehydes
    Prasad, KRK
    Joshi, NN
    TETRAHEDRON-ASYMMETRY, 1996, 7 (07) : 1957 - 1960
  • [36] Synthesis and Application of C2-Symmetric Chiral Diol on the Enantioselective Addition of Diethylzinc to Aldehydes
    王锐
    杨晓武
    沈健恒
    达朝山
    粟武
    王恒山
    陈新滋
    厦门大学学报(自然科学版), 1999, (S1) : 161 - 161
  • [37] Enantioselective addition of diethylzinc to aromatic aldehydes catalyzed by new chiral oxazolidine ligand
    Kang, YF
    Liu, L
    Wang, R
    Ni, M
    Han, ZJ
    SYNTHETIC COMMUNICATIONS, 2005, 35 (13) : 1819 - 1823
  • [38] Enantioselective addition of diethylzinc to aldehydes induced by a new chiral Ti(IV) catalyst
    Hwang, CD
    Uang, BJ
    TETRAHEDRON-ASYMMETRY, 1998, 9 (22) : 3979 - 3984
  • [39] New chiral ligands derived from (+) and (-)-α-pinene for the enantioselective addition of diethylzinc to aldehydes
    Frensch, Gustavo
    Labes, Ricardo
    Wosch, Celso Luiz
    Munaretto, Laieli dos Santos
    Salome, Kahlil Schwanka
    Guerrero, Palimecio G., Jr.
    Marques, Francisco A.
    TETRAHEDRON LETTERS, 2016, 57 (03) : 420 - 422
  • [40] New chiral pyrrolidinyl- and 2-azanorbornyloxazolidine ligands for enantioselective addition of diethylzinc to aldehydes
    Nakano, H
    Okuyama, Y
    Fushimi, K
    Yamakawa, R
    Kayaoka, D
    Hongo, H
    HETEROCYCLES, 2002, 56 (1-2) : 457 - 466