A comment on the formation of N-C bonds via reactions of anionic dinitrogen complexes with organic halides: X-ray crystallographic structure of trans-[W(CN)(NNCHOCH2CH2CH2)(dppe)(2)]

被引：3
|
作者：
Hughes, DL [1 ]
Ibrahim, SK [1 ]
Ali, HM [1 ]
Pickett, CJ [1 ]
机构：
[1] JOHN INNES CTR PLANT SCI RES,NITROGEN FIXAT LAB,NORWICH NR4 7UH,NORFOLK,ENGLAND
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 519卷 / 1-2期
关键词：
dinitrogen complexes; tungsten; silicon; crystal structure; diazenides;
D O I：
10.1016/S0022-328X(96)06173-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of trans-[W(N-2)(CN)(dppe)(2)](-) with Me(3)SiCH(2)I in tetrahydrofuran gives a tetrahydrofuranyldiazenide product, trans-[W(CN)(NNCHOCH2CH2CH2)(dppe)(2)], the formation of which confirms that N-C bond formation involving reactions between anionic dinitrogen complexes and organic halides can occur by a single electron transfer/radical coupling mechanism. The structure of the diazenide was established crystallographically.
引用
收藏
页码：273 / 275
页数：3
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