Mesoscopic field theory of ionic systems

被引:25
|
作者
Ciach, A
Stell, G
机构
[1] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland
[2] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA
来源
关键词
ionic systems; phase transitions; critical phenomena;
D O I
10.1142/S0217979205032176
中图分类号
O59 [应用物理学];
学科分类号
摘要
A mesoscopic field theory for the primitive model of ionic systems with additional, short-range interactions is presented. Generic models in continuum space and with positions of the ions restricted to lattice sites of various lattices are described in detail. We describe briefly the field-theoretic methods and review the foundations of the mesoscopic description. The types of phase diagrams predicted by our theory for different versions of the model are presented and discussed. They all agree with recent simulations. On the quantitative level our theory yields an RPM tricritical-point location on the sc lattice which is in good agreement with the simulation results. Arguments indicating that the critical point in the RPM belongs to the Ising universality class are given.
引用
收藏
页码:3309 / 3343
页数:35
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