Nickel complex-mediated synthesis of optically active wholly aromatic polyketones bearing 2,2′-dimethoxy-1,1′-binaphthyl-6,6′-ene units

被引：25

作者：

Maeyama, K ^{[1
]}

Ogura, K

Okamoto, A

Ogino, K

Saito, H

Yonezawa, N

机构：

[1] Tokyo Univ Agr & Technol, Grad Sch, Dept Organ & Polymer Mat Chem, Koganei, Tokyo 1848588, Japan

[2] Tokyo Univ Agr & Technol, Grad Sch Bioapplicat & Syst Engn, Koganei, Tokyo 1848588, Japan

来源：

POLYMER JOURNAL | 2005年 / 37卷 / 10期

关键词：

2,2 '-dimethoxybinaphthyl; nickel complex-mediated aromatic coupling polymerization; wholly aromatic polyketone; excellent solubility; optically active polyketones;

D O I：

10.1295/polymj.37.736

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

6,6'-Bis(chlorobenzoyl)-2,2'-dimethoxy-1,1'-binaphthyls 2a and 2b are prepared via P2O5-MsOH mediated regioselective diaroylation of 2,2'-dimethoxy-1,1'-binaphthyl (1). NiBr2/Zn-mediated aromatic coupling polymerization of 6,6-bis(chlorobenzoyl)-2,2'-dimethoxy-1,1'-binaphthyls 2 yields the corresponding wholly aromatic polyketones. When optically active bis(chlorobenzoylated) binaphthyls (2) are employed, optically active wholly aromatic polyketones 3 with large specific rotations, excellent thermal resistance, and excellent solubility to organic solvents are obtained.

引用

页码：736 / 741

页数：6

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