Optical properties of sol-gel derived ZrO2-TiO2 composite films

被引:40
|
作者
Liang, Liping
Sheng, Yonggang
Xu, Yao [1 ]
Wu, Dong
Sun, Yuhan
机构
[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
[2] Taiyuan Univ Sci & Technol, Coll Mat Sci & Engn, Taiyuan 030024, Peoples R China
[3] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
关键词
ZrO2-TiO2; sol-gel coating; optical properties; structural properties;
D O I
10.1016/j.tsf.2007.03.142
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Compositional dependences of the optical properties of sol-gel derived ZrO2-TiO2 composite films (with molar ratio of Ti:Zr ranging from 0:10 to 10:0) have been studied. The refractive index, absorption coefficient, and optical band gap were determined from the corresponding transmission spectra based on Swanepoel's method. It was found that the optical properties of the composite films could be easily tailored in a wide range by a simple control on the system composition. As the molar ratio of Ti:Zr increased from 0:10 to 10:01 a clear increase of the refractive index from 1.912 to 2.263 (at 633 nm) was observed. Simultaneously, the optical band gap decreased monotonically from 5.26 to 3.25 eV Combined with the X-ray diffraction analysis, the observed variations in both the refractive index and optical band gap have been directly correlated with the structural evolution of the composite films. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:7765 / 7771
页数:7
相关论文
共 50 条
  • [41] Optical absorption behavior of ZrO2-TiO2 nanolaminate films
    Aita, CR
    DeLoach, JD
    Sorbello, RS
    JOURNAL OF APPLIED PHYSICS, 2003, 94 (01) : 654 - 663
  • [42] Optical properties of sol-gel derived ferroelectric films
    Journal of Non-Crystalline Solids, 1995, 187
  • [43] Fabrication of high performance ZrO2-TiO2 NF membranes via a modified colloidal sol-gel process
    Lu, Yawei
    Chen, Xianfu
    Wen, Juanjuan
    Qiu, Minghui
    Fan, Yiqun
    Huagong Xuebao/CIESC Journal, 2015, 66 (09): : 3769 - 3775
  • [44] Sol-gel derived TiO2:ZrO2 multilayer thin films for humidity sensing application
    Biju, Kuyyadi P.
    Jain, Mahaveer K.
    SENSORS AND ACTUATORS B-CHEMICAL, 2008, 128 (02) : 407 - 413
  • [45] The effect of processing variables on structural changes and optical properties of SiO2-TiO2 sol-gel derived films
    Whang, CM
    Lim, SS
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2000, 21 (12) : 1181 - 1186
  • [46] Surface properties of sol-gel processed TiO2-SiO2 amorphous composite films
    Lee, Chul-Sung
    Kim, Eun-Kyeong
    Kim, Ji-Yeong
    Kim, Sang Sub
    METALS AND MATERIALS INTERNATIONAL, 2012, 18 (05) : 869 - 873
  • [47] Surface properties of sol-gel processed TiO2-SiO2 amorphous composite films
    Chul-Sung Lee
    Eun-Kyeong Kim
    Ji-Yeong Kim
    Sang Sub Kim
    Metals and Materials International, 2012, 18 : 869 - 873
  • [48] Synthesis of mixed ZrO2-TiO2 oxides by sol-gel:: Microstructural characterization and infrared spectroscopy studies of NOx
    Perez-Hernandez, R.
    Mendoza-Anaya, D.
    Fernandez, M. E.
    Gomez-Cortes, A.
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 281 (1-2) : 200 - 206
  • [49] Optical constants of sol-gel derived TiO2 films characterized by spectroscopic ellipsometry
    Wang Xiao-Dong
    Shen Jun
    Wang Sheng-Zhao
    Zhang Zhi-Hua
    ACTA PHYSICA SINICA, 2009, 58 (11) : 8027 - 8032
  • [50] Investigation of sol-gel derived ZrO2 thin films by nanoindentation
    Lucca, DA
    Klopfstein, M
    Ghisleni, R
    Gude, A
    Mehner, A
    Datchary, W
    CIRP ANNALS-MANUFACTURING TECHNOLOGY, 2004, 53 (01): : 475 - 478