Additive Manufacturing of Degradable Materials via Ring-Opening Metathesis Polymerization (ROMP)

被引：15

作者：

Leguizamon, Samuel C. ^{[1
]}

Lyons, Kenneth ^{[1
]}

Monk, Nicolas T. ^{[1
]}

Hochrein, Madison T. ^{[1
]}

Jones, Brad H. ^{[1
]}

Foster, Jeffrey C. ^{[1
]}

机构：

[1] Sandia Natl Labs, Albuquerque, NM 87185 USA

来源：

ACS APPLIED MATERIALS & INTERFACES | 2022年 / 14卷 / 45期

关键词：

ring-opening metathesis polymerization (ROMP); additive manufacturing (AM); stereolithography (SLA); photochemistry; photopolymerization; degradable materials; polymer degradation;

D O I：

10.1021/acsami.2c14411

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Thermoset materials comprise a significant proportion of high -performance plastics due to their shape permanence and excellent thermal and mechanical properties. However, these properties come at the expense of degradability. Here, we show for the first time that the industrial thermoset polydicyclopentadiene (PDCPD) can be additively manufactured (AM) with degradable 2,3-dihydrofuran (DHF) linkages using a photochemical approach. Treatment of the manufactured objects with acid results in rapid degradation to soluble byproducts. This work highlights the potential of ring-opening metathesis polymerization (ROMP) chemistry to create degradable materials amenable to advanced manufacturing processes.

引用

页码：51301 / 51306

页数：6

共 50 条

[21] Progress of Application of Ring-Opening Metathesis Polymerization (ROMP) in the Synthesis of Star Polymers
Zhou Chulu
Hou Cuiping
Chen Wei
Wang Lijie
Cheng Jianhua
ACTA CHIMICA SINICA, 2022, 80 (02) : 229 - 236
[22] Ring-opening metathesis polymerization (ROMP) of norbornenyl-functionalized fatty alcohols
Xia, Ying
Lu, Yongshang
Larock, Richard C.
POLYMER, 2010, 51 (01) : 53 - 61
[23] SUBSTITUTED POLYACETYLENES THROUGH THE RING-OPENING METATHESIS POLYMERIZATION (ROMP) OF SUBSTITUTED CYCLOOCTATETRAENES
GORMAN, CB
GINSBURG, EJ
KLAVETTER, FL
GRUBBS, RH
MARDER, SR
PERRY, JW
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1989, 197 : 126 - INOR
[24] OLEFIN METATHESIS AND RING-OPENING METATHESIS POLYMERIZATION (ROMP) BY WELL-DEFINED RHENIUM COMPLEXES
VAUGHAN, GA
SCHROCK, RR
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 204 : 503 - INOR
[25] Optimization of ring-opening metathesis polymerization (ROMP) under physiologically relevant conditions
Church, Derek C.
Takiguchi, Lauren
Pokorski, Jonathan K.
POLYMER CHEMISTRY, 2020, 11 (27) : 4492 - 4499
[26] Preparation of Bottlebrush Polymers via a One-Pot Ring-Opening Polymerization (ROP) and Ring-Opening Metathesis Polymerization (ROMP) Grafting-Through Strategy
Radzinski, Scott C.
Foster, Jeffrey C.
Matson, John B.
MACROMOLECULAR RAPID COMMUNICATIONS, 2016, 37 (07) : 616 - 621
[27] Metallosupramolecular polymers via ring-opening metathesis polymerization
Elacqua, Elizabeth
Weck, Marcus
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
[28] Ring-opening polymerization of degradable polyesters
Stridsberg, K
Gruvegard, M
Albertsson, AC
MACROMOLECULAR SYMPOSIA, 1998, 130 : 367 - 378
[29] Ring-Opening Metathesis Polymerization to Access Degradable Imine-Based Polymers
Li, Wu
Cheng, Si-Jia
Li, You-Gui
Khan, Muhammad Asadullah
Chen, Min
CHINESE JOURNAL OF POLYMER SCIENCE, 2024,
[30] Fabrication of polymer nanoparticles via intrachain ring-opening metathesis polymerizations (ROMP)
Benware, Sarah
Chen, Ruiwen
Cole, Justin
Berda, Erik
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255

← 1 2 3 4 5 →