Extended π-conjugated ruthenium zinc-porphyrin complexes with enhanced nonlinear-optical properties

被引：50

作者：

de Torres, Miriam ^{[1
]}

Semin, Sergey ^{[1
]}

Razdolski, Ilya ^{[1
]}

Xu, Jialiang ^{[1
]}

Elemans, Johannes A. A. W. ^{[1
]}

Rasing, Theo ^{[1
]}

Rowan, Alan E. ^{[1
]}

Nolte, Roeland J. M. ^{[1
]}

机构：

[1] Radboud Univ Nijmegen, Inst Mol & Mat, NL-6525 AJ Nijmegen, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 14期

基金：

欧洲研究理事会;

关键词：

MOLECULAR MATERIALS; COORDINATION; LIGANDS; SYSTEMS;

D O I：

10.1039/c4cc09592h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zinc porphyrin dimers and trimers, in which the porphyrins are connected via a ruthenium metal core, exhibit large third-order nonlinear optical absorption coefficients and refractive indices. These properties are a result of the presence of multiple porphyrins, which lead to an extension of the pi-conjugated system and the octupolar effect.

引用

页码：2855 / 2858

页数：4

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