C-O bond hydrogenolysis vs. C=C group hydrogenation of furfuryl alcohol: towards sustainable synthesis of 1,2-pentanediol

被引：25
|
作者：
Goetz, Dominik [1 ]
Lucas, Martin [1 ]
Claus, Peter [1 ]
机构：
[1] Tech Univ Darmstadt, Dept Chem, Ernst Berl Inst Chem Technol 2, Alarich Weiss Str 8, D-64287 Darmstadt, Germany
来源：
REACTION CHEMISTRY & ENGINEERING | 2016年 / 1卷 / 02期
关键词：
TETRAHYDROFURFURYL ALCOHOL; CATALYST; CYCLOPENTANONE; REARRANGEMENT; CONVERSION; KINETICS; PHASE;
D O I：
10.1039/c5re00026b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The conversion of furfuryl alcohol into 1,2-pentanediol and tetrahydrofurfuryl alcohol by aqueous phase hydrogenolysis using highly active supported ruthenium catalysts is a promising sustainable route substituting for petro-based production processes. An on-line analysis of the reaction, performed by ATR-IR spectroscopy, is necessary to show the formation of solid deposits during the reaction.
引用
收藏
页码：161 / 164
页数：4
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