NIR Raman studies of superionic phase transition in (NH4)(4)H-2(SeO4)(3)

被引：13
|
作者：
Polomska, M
机构：
[1] Institute of Molecular Physics, Polish Academy of Sciences, 60-179 Poznań
来源：
JOURNAL OF MOLECULAR STRUCTURE | 1997年 / 404卷 / 1-2期
关键词：
Raman spectroscopy; molecular group dynamics; phase transition; tetraammonium dihydrogen triselenate; superionic phase;
D O I：
10.1016/S0022-2860(96)09379-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Near-infrared Fourier transform Raman spectroscopy has been used to study the molecular group dynamics in (NH4)(4)H-2(SeO4)(3) single crystal in the vicinity of its superionic phase transition (T-s similar or equal to 378 K). A change in the dynamics of SeO4 and SeO4H entities begins about 15 K below T-s and ends at T-s. The results of the Raman studies of (NH4)(4)H-2(SeO4)(3) gave evidence that the orientational disorder of SeO4 tetrahedra is responsible for the fast protonic conductivity. A very large temperature hysteresis (similar to 30 K) for the superionic phase transition in (NH4)(4)H-2(SeO4)(3) was found. (C) 1997 Elsevier Science B.V.
引用
收藏
页码：181 / 186
页数：6
相关论文
共 50 条
  • [31] Phase behaviour and superionic phase transition in K3H(SeO4)2
    Hernandez-Daguer, O. S.
    Correa, H.
    Vargas, R. A.
    IONICS, 2015, 21 (08) : 2201 - 2209
  • [32] Phase behaviour and superionic phase transition in K3H(SeO4)2
    O. S. Hernández-Daguer
    H. Correa
    R. A. Vargas
    Ionics, 2015, 21 : 2201 - 2209
  • [33] Surface Evolution at the Phase Transitions in (NH4)3H(SeO4)2 Crystals
    R. V. Gainutdinov
    A. L. Tolstikhina
    E. V. Selezneva
    I. P. Makarova
    Crystallography Reports, 2021, 66 : 508 - 513
  • [34] Surface Evolution at the Phase Transitions in (NH4)3H(SeO4)2 Crystals
    Gainutdinov, R., V
    Tolstikhina, A. L.
    Selezneva, E., V
    Makarova, I. P.
    CRYSTALLOGRAPHY REPORTS, 2021, 66 (03) : 508 - 513
  • [35] Discontinuous narrowing of VO2+ electron spin resonance linewidth in (NH4)3H(SeO4)2 induced by superionic phase transition
    Furukawa, K
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2000, 39 (5A): : 2608 - 2609
  • [36] Discontinuous narrowing of VO2+ electron spin resonance linewidth in (NH4)3H(SeO4)2 induced by superionic phase transition
    Furukawa, Kazuo
    2000, JJAP, Tokyo, Japan (39):
  • [37] Dielectric Nonlinearity of (NH4)3H(SeO4)2 Crystal
    Jankowski, M.
    Cach, R.
    Dacko, S.
    Czapla, Z.
    FERROELECTRICS, 2012, 426 : 72 - 80
  • [38] Ferroelastic domain structure of (NH4)(3)H(SeO4)(2) crystal
    Stasyuk, IV
    Pavlenko, N
    Polomska, M
    PHASE TRANSITIONS, 1997, 62 (03) : 167 - &
  • [39] Effect of phase transition sequence on the ferroelastic domain structure of (NH4)(3)H(SeO4)(2) at room temperature
    Polomska, M
    Augustyniak, MA
    FERROELECTRICS, 1997, 190 (1-4) : 113 - 118
  • [40] Rhombohedral-rhombohedral phase transition of the proton conductor (NH4)3 H(SeO4)2 at 337 K
    TU Berlin, Berlin, Germany
    Solid State Ionics, 3-4 (275-282):
12345