Spin-frustrated organic-inorganic hybrids of lindgrenite

被引：55
|
作者：
Shores, MP [1 ]
Bartlett, BM [1 ]
Nocera, DG [1 ]
机构：
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 51期
关键词：
D O I：
10.1021/ja056666g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report the syntheses and magnetic properties of hybrid organic-inorganic materials that represent layer-expanded versions of the rare mineral lindgrenite (Cu3(OH)2(MoO4)2). The structures of these compounds feature one-dimensional chains of alternating corner- and edge-sharing Cu(II) triangles. By expanding the inorganic layers of lindgrenite with 4,4′-bipyridine, spin-frustrated antiferromagnetism is revealed by a change of the spin frustration parameter f from 1.2 in lindgrenite to 19.4 in (4,4′-bpy)Cu3(OH)2(MoO4)2. Copyright © 2005 American Chemical Society.
引用
收藏
页码：17986 / 17987
页数：2
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