Reaction of tri- and tetrasubstituted alkenes with the low-temperature oxidizing system aluminum tert-butylate-tert-butyl hydroperoxide

被引：3
|
作者：
Martynova, IM [1 ]
Stepovik, LP [1 ]
Dodonov, VA [1 ]
机构：
[1] NI Lobachevskii State Univ, Nizhnii Novgorod, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2001年 / 71卷 / 05期
关键词：
D O I：
10.1023/A:1012357318443
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The system consisting of aluminum tert-butylate and tert-butyl hydroperoxide under rnild conditions (20 degreesC) oxidizes tri- and tetrasubstituted ethylenes containing at least one alpha -methyl group. The reaction proceeds via formation of tertiary allylic hydroperoxides and their subsequent transformations into unsaturated alcohols and epoxy alcohols, and also into carbonyl compounds. The presence of the latter products suggests degradation of the carbon skeleton of alkenes.
引用
收藏
页码：736 / 741
页数：6
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