Metal Salts of 3,3′-Diamino-4,4′-dinitramino-5,5′-bi-1,2,4-triazole in Pyrotechnic Compositions

被引：11
|
作者：
Glueck, Johann [1 ]
Gospodinov, Ivan [1 ]
Klapoetke, Thomas M. [1 ]
Stierstorfer, Joerg [1 ]
机构：
[1] Ludwig Maximilians Univ Munchen, Dept Chem, Butenandtstr 9 D, D-80539 Munich, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2019年 / 645卷 / 03期
关键词：
Pyrotechnics; Chlorine-free; High-nitrogen compound; Structure elucidation; Red colorant; HIGH-NITROGEN-COMPOUNDS; ALKALI-METAL; COLORANTS; STRONTIUM; PERFORMANCE;
D O I：
10.1002/zaac.201800179
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of alkali and alkaline earth salts of 3,3-diamino-4,4-dinitramino-5,5-bi-1,2,4-triazole (H(2)ANAT) is reported. The fast and convenient three steps reaction toward the target compounds does not require any organic solvents. In addition to an intensive characterization of all synthesized metal salts, the focus was on developing chlorine and nitrate-free red-light-generating pyrotechnical formulations. Strontium 3,3-diamino-4,4-dinitramino-5,5-bitriazolate hexahydrate served as colorant and oxidizer in one molecule. The energetic properties of all developed pyrotechnical formulations assure safe handling and manufacturing.
引用
收藏
页码：370 / 376
页数：7
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