Vacuum-ultraviolet photolysis of H3CF in solid neon: Infrared spectra of HCF and CF+

被引：11

作者：

Wu, Yu-Jong ^{[1
]}

Chen, Hui-Fen ^{[1
]}

Chou, Sheng-Lung ^{[1
]}

Lin, Meng-Yeh ^{[1
]}

Cheng, Bing-Ming ^{[1
]}

机构：

[1] Natl Synchrotron Radiat Res Ctr, Hsinchu 30076, Taiwan

来源：

CHEMICAL PHYSICS LETTERS | 2010年 / 497卷 / 1-3期

关键词：

HALOCARBENE ANIONS HCF; COUPLED-CLUSTER; PHOTOELECTRON-SPECTROSCOPY; VIBRATIONAL-SPECTRUM; EXCITATION-ENERGIES; MATRIX; PHOTODISSOCIATION; DISTRIBUTIONS; STATE; CH3F;

D O I：

10.1016/j.cplett.2010.07.087

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Irradiation of a sample containing fluoromethane dispersed in solid neon near 3.0 K with light from a synchrotron at wavelength 124 nm generated products that were detected with infrared absorption spectra. The identified products include CF, CF+, CF2, HCF, H2CF, C2F2, C2F2H2, CH3, CH, C2H2 and HF. Isotopic labeling with C-13 and deuterium and quantum-chemical calculations confirmed the identification of these species; the vibrational spectra of CF+ and HCF (CH stretching mode) are recorded for the first time in solid neon. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：12 / 17

页数：6

共 49 条

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