Synthesis of Task Specific and Reusable Protic Ionic Liquids for One-Pot Multicomponent Syntheses

被引：1
|
作者：
Sardar, Sabahat [1 ]
Wilfred, Cecilia Devi [1 ]
Marc, Leveque Jean [1 ]
机构：
[1] Univ Teknol PETRONAS, Dept Fundamental & Appl Sci, Tronoh, Perak, Malaysia
来源：
PROCEEDING OF THE 4TH INTERNATIONAL CONFERENCE OF FUNDAMENTAL AND APPLIED SCIENCES 2016 (ICFAS2016) | 2016年 / 1787卷
关键词：
MANNICH REACTION; AROMATIC-ALDEHYDES;
D O I：
10.1063/1.4968075
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
Protic ionic liquids (ILs) synthesized from 1-methylimidazole with 1,3-propane sultone and 1,4-butane sultone catalyzed Mannich reaction at 25 degrees C to afford Mannich bases in high yield (76%) and less time duration (20 min). Ionic liquids have been used as dual reagent i.e., as catalyst as well as solvent. Simple extraction by water separated ionic liquid from reaction mixture with 4 times recycling without any significant loss in activity.
引用
收藏
页数：7
相关论文
共 50 条
  • [1] One-Pot Multicomponent Synthesis of Imidazole Rings in Acidic Ionic Liquids: A Review
    Eze, Cosmas Chinweike
    Ezeokonkwo, Mercy Amarachi
    Ezema, Benjamin Ebere
    Onoabedje, Abraham Efeturi
    Ibeanu, Fidelia Ngozika
    Ugwu, David Izuchukwu
    Onyeyilim, Leonard Ebuka
    Ezugwu, James Anayochwkwu
    MINI-REVIEWS IN ORGANIC CHEMISTRY, 2020, 17 (08) : 975 - 990
  • [2] Multicomponent and One-pot Syntheses of Quinoxalines
    Biesen, Lukas
    Mueller, Thomas J. J.
    ADVANCED SYNTHESIS & CATALYSIS, 2021, 363 (04) : 980 - 1006
  • [3] One-Pot Synthesis of Luminescent Polymer-Nanoparticle Composites from Task-Specific Ionic Liquids
    Campbell, Paul S.
    Lorbeer, Chantal
    Cybinska, Joanna
    Mudring, Anja-Verena
    ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (23) : 2924 - 2931
  • [4] Task-specific basic ionic liquid: A reusable and green catalyst for one-pot synthesis of highly functionalized pyrroles in aqueous media
    Yavari, Issa
    Kowsari, Elaheh
    SYNLETT, 2008, (06) : 897 - 899
  • [5] One-pot synthesis of 3-substituted indole derivatives using moisture stable, reusable, and task specific ionic liquid catalysts
    Ravindran, Anaswara
    Kore, Rajkumar
    Srivastava, Rajendra
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2013, 52 (01): : 129 - 135
  • [6] One-pot construction of dihydropyrimidinones in ionic liquids
    Bahekar, SS
    Kotharkar, SA
    Shinde, DB
    MENDELEEV COMMUNICATIONS, 2004, 14 (05) : 210 - 212
  • [7] One-pot synthesis of levulinic acid from cellulose in ionic liquids
    Shen, Yue
    Sun, Jian-Kui
    Yi, Yu-Xuan
    Wang, Bo
    Xu, Feng
    Sun, Run-Cang
    BIORESOURCE TECHNOLOGY, 2015, 192 : 812 - 816
  • [8] One-pot and solventless synthesis of ionic liquids under ultrasonic irradiation
    Estager, Julien
    Leveque, Jean-Marc
    Cravotto, Giancarlo
    Boffa, Luisa
    Bonrath, Werner
    Draye, Micheline
    SYNLETT, 2007, (13) : 2065 - 2068
  • [9] One-pot integrated biofuel production using low-cost biocompatible protic ionic liquids
    Sun, Jian
    Konda, N. V. S. N. Murthy
    Parthasarathi, Ramakrishnan
    Dutta, Tanmoy
    Valiev, Marat
    Xu, Feng
    Simmons, Blake A.
    Singh, Seema
    GREEN CHEMISTRY, 2017, 19 (13) : 3152 - 3163
  • [10] Simple one-pot process for the bioresolution of tertiary amino ester protic ionic liquids using subtilisin
    Brossat, Maude
    Moody, Thomas S.
    Taylor, Stephen J. C.
    Wiffen, Jonathan W.
    TETRAHEDRON-ASYMMETRY, 2009, 20 (18) : 2112 - 2116
12345