Enhanced Copolymer Gel Modified by Dual Surfactants for Flexible Zinc-Air Batteries

被引:24
|
作者
Zhang, Pengfei [1 ]
Wang, Keliang [1 ,2 ]
Zuo, Yayu [1 ]
Wei, Manhui [1 ]
Wang, Hengwei [1 ]
Chen, Zhuo [1 ]
Shang, Nuo [1 ]
Pei, Pucheng [2 ]
机构
[1] Beijing Inst Technol, Sch Mech Engn, Beijing 100081, Peoples R China
[2] Tsinghua Univ, State Key Lab Automot Safety & Energy, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
zinc-air batteries; gel electrolytes; dual surfactants; temperature adaptability; high performance; POLYMER ELECTROLYTE; OXIDE; HYDROGELS; ACID; F127;
D O I
10.1021/acsami.2c13625
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Zinc-air batteries using gels as carriers for electrolyte absorption have attracted extensive attention due to their flexibility, deformability, and high specific capacity. However, traditional mono-polymer gel electrolytes display poor mechanical properties and low ionic conductivity at wide-window temperatures. Here, the enhanced gel polymer (PAM-F/G) modified by dual surfactants is present by way of pluronic F127 and layered graphene oxide introduced into the polyacrylamide (PAM) matrix. The gel electrolyte procured by absorbing 6 M KOH exhibits improved mechanical characteristics, temperature adaptability, and a satisfactory ionic conductivity (276 mS cm-1). The results demonstrate that a flexible zinc-air battery assembled by PAM-F/G electrolyte outputs a high power density (155 mW cm-2) and can even operate reliably (>40 h) at -20 degrees C. These findings are available for promoting the research and popularization of flexible zinc-air batteries with high performance.
引用
收藏
页码:49109 / 49118
页数:10
相关论文
共 50 条
  • [21] Aqueous fibrous membrane electrolyte for ultrathin flexible Zinc-air batteries
    Zhao, Xiaohui
    Wei, Xinmin
    He, Mengxue
    Cheng, Haoran
    Hu, Jiapeng
    Zhang, Yanzhi
    Qin, Yongze
    Peng, Yang
    Deng, Zhao
    CHEMICAL ENGINEERING JOURNAL, 2024, 500
  • [22] Key materials and structural design in flexible and stretchable zinc-air batteries
    Li, Wenzheng
    Cheng, Lukuan
    Chen, Xiaoyang
    Liu, Youfa
    Liu, Yao
    Liu, Qingjiang
    Huang, Yan
    NANO ENERGY, 2023, 106
  • [23] Bacterial cellulose hydrogel: A promising electrolyte for flexible zinc-air batteries
    Zhang, Yanan
    Chen, Yajun
    Li, Xin
    Alfred, Mensah
    Li, Dawei
    Huang, Fenglin
    Wei, Qufu
    JOURNAL OF POWER SOURCES, 2021, 482
  • [24] Bacterial cellulose hydrogel: A promising electrolyte for flexible zinc-air batteries
    Zhang, Yanan
    Chen, Yajun
    Li, Xin
    Alfred, Mensah
    Li, Dawei
    Huang, Fenglin
    Wei, Qufu
    Journal of Power Sources, 2022, 482
  • [25] Construction of Alkaline Gel Polymer Electrolytes with a Double Cross-Linked Network for Flexible Zinc-Air Batteries
    Zhang, Guotao
    Cai, Xiaoxia
    Li, Cong
    Yao, Jinshui
    Liu, Weiliang
    Qiao, Congde
    Li, Guangda
    Wang, Qiang
    Han, Jingjie
    ACS APPLIED POLYMER MATERIALS, 2023, 5 (05) : 3622 - 3631
  • [26] Agar-PVA/GO double network gel electrolyte for high performance flexible zinc-air batteries
    Yang, Yue
    Wang, Tao
    Guo, Yong
    Liu, Penggao
    Han, Xiaofeng
    Wu, Dongling
    MATERIALS TODAY CHEMISTRY, 2023, 29
  • [27] Advanced dual-atom catalysts for rechargeable zinc-air batteries
    Lin X.
    Chen G.
    Zhu Y.
    Huang H.
    Energy Reviews, 2024, 3 (03):
  • [28] Enhanced Low-Temperature Durability of Flexible Zinc-Air Batteries Using NaCl-Doped Dual-Network Hydrogel Electrolytes
    Ye, Zisen
    Yang, Mingcheng
    Guo, Yaxin
    Chen, Yu
    Zhang, Benshang
    Liu, Shubo
    Chen, Yang
    Guo, Wenhui
    ACS APPLIED POLYMER MATERIALS, 2024, 6 (19): : 11901 - 11910
  • [29] Batteries: From Alkaline to Zinc-Air
    Dondelinger, Robert M.
    Biomedical Instrumentation and Technology, 2004, 38 (02): : 100 - 110
  • [30] Kinetic-enhanced carbon fiber for rechargeable zinc-air batteries
    Li, Yang
    Wang, Bin
    Wang, Hao-Fan
    Tang, Cheng
    JOURNAL OF CHEMICAL PHYSICS, 2023, 158 (04):