Enhanced Copolymer Gel Modified by Dual Surfactants for Flexible Zinc-Air Batteries

被引:24
|
作者
Zhang, Pengfei [1 ]
Wang, Keliang [1 ,2 ]
Zuo, Yayu [1 ]
Wei, Manhui [1 ]
Wang, Hengwei [1 ]
Chen, Zhuo [1 ]
Shang, Nuo [1 ]
Pei, Pucheng [2 ]
机构
[1] Beijing Inst Technol, Sch Mech Engn, Beijing 100081, Peoples R China
[2] Tsinghua Univ, State Key Lab Automot Safety & Energy, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
zinc-air batteries; gel electrolytes; dual surfactants; temperature adaptability; high performance; POLYMER ELECTROLYTE; OXIDE; HYDROGELS; ACID; F127;
D O I
10.1021/acsami.2c13625
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Zinc-air batteries using gels as carriers for electrolyte absorption have attracted extensive attention due to their flexibility, deformability, and high specific capacity. However, traditional mono-polymer gel electrolytes display poor mechanical properties and low ionic conductivity at wide-window temperatures. Here, the enhanced gel polymer (PAM-F/G) modified by dual surfactants is present by way of pluronic F127 and layered graphene oxide introduced into the polyacrylamide (PAM) matrix. The gel electrolyte procured by absorbing 6 M KOH exhibits improved mechanical characteristics, temperature adaptability, and a satisfactory ionic conductivity (276 mS cm-1). The results demonstrate that a flexible zinc-air battery assembled by PAM-F/G electrolyte outputs a high power density (155 mW cm-2) and can even operate reliably (>40 h) at -20 degrees C. These findings are available for promoting the research and popularization of flexible zinc-air batteries with high performance.
引用
收藏
页码:49109 / 49118
页数:10
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