Formation of well-defined p-tent-butylcalix[4]arenedithiolate monolayers on a Au(100)-(1 x 1) surface studied by in situ scanning tunneling microscopy

被引：11

作者：

Yoshimoto, S

Abe, M

Itaya, K

Narumi, F

Sashikata, K

Nishiyama, K

Taniguchi, I

机构：

[1] Tohoku Univ, Grad Sch Engn, Dept Appl Chem, Sendai, Miyagi 9808579, Japan

[2] Japan Sci & Technol, CREST, Kawaguchi, Saitama 3320012, Japan

[3] Ishinomaki Senshu Univ, Dept Basic Sci, Sch Sci & Engn, Ishinomaki 9868580, Japan

[4] Kumamoto Univ, Dept Appl Chem & Biochem, Fac Engn, Kumamoto 8608555, Japan

来源：

LANGMUIR | 2003年 / 19卷 / 20期

关键词：

D O I：

10.1021/la034819c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

p-tent-Butylcalix[4]arene-1,3-dithiol (BCAD) was synthesized to prepare a functionalized surface for host-guest molecular recognition by immobilizing it on the Au(100)-(1 x 1) surface in 0.05 M HClO4. In situ scanning tunneling microscopy (STM) was employed to investigate the structure of the adlayer of BCAD formed on the Au(100)-(1 x 1) surface. Highly ordered adlayers of BCAD with two different packing arrangements were found to form on the Au(100)-(1 x 1) surface. High-resolution STM images revealed the packing arrangement and even the internal molecular structure of BCAD.

引用

页码：8130 / 8133

页数：4

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