Formation of well-defined p-tent-butylcalix[4]arenedithiolate monolayers on a Au(100)-(1 x 1) surface studied by in situ scanning tunneling microscopy

被引：11
|
作者：
Yoshimoto, S
Abe, M
Itaya, K
Narumi, F
Sashikata, K
Nishiyama, K
Taniguchi, I
机构：
[1] Tohoku Univ, Grad Sch Engn, Dept Appl Chem, Sendai, Miyagi 9808579, Japan
[2] Japan Sci & Technol, CREST, Kawaguchi, Saitama 3320012, Japan
[3] Ishinomaki Senshu Univ, Dept Basic Sci, Sch Sci & Engn, Ishinomaki 9868580, Japan
[4] Kumamoto Univ, Dept Appl Chem & Biochem, Fac Engn, Kumamoto 8608555, Japan
来源：
LANGMUIR | 2003年 / 19卷 / 20期
关键词：
D O I：
10.1021/la034819c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
p-tent-Butylcalix[4]arene-1,3-dithiol (BCAD) was synthesized to prepare a functionalized surface for host-guest molecular recognition by immobilizing it on the Au(100)-(1 x 1) surface in 0.05 M HClO4. In situ scanning tunneling microscopy (STM) was employed to investigate the structure of the adlayer of BCAD formed on the Au(100)-(1 x 1) surface. Highly ordered adlayers of BCAD with two different packing arrangements were found to form on the Au(100)-(1 x 1) surface. High-resolution STM images revealed the packing arrangement and even the internal molecular structure of BCAD.
引用
收藏
页码：8130 / 8133
页数：4
相关论文
共 50 条
  • [1] Oxide formation on Si(100)-2x1 surfaces studied by scanning tunneling microscopy scanning tunneling spectroscopy
    Ikegami, H
    Ohmori, K
    Ikeda, H
    Iwano, H
    Zaima, S
    Yasuda, Y
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1996, 35 (2B): : 1593 - 1597
  • [2] SURFACE ALLOY FORMATION STUDIED BY SCANNING TUNNELING MICROSCOPY - CU(100) + AU-C(2 X-2)
    CHAMBLISS, DD
    CHIANG, S
    SURFACE SCIENCE, 1992, 264 (1-2) : L187 - L192
  • [3] Oxide formation on Si(100)-2×1 surfaces studied by scanning tunneling microscopy/scanning tunneling spectroscopy
    Ikegami, Hiroshi
    Ohmori, Kenji
    Ikeda, Hiroya
    Iwano, Hirotaka
    Zaima, Shigeaki
    Yasuda, Yukio
    Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes & Review Papers, 1996, 35 (2 B): : 1593 - 1597
  • [4] In situ scanning tunneling microscopy of well-defined Ir(111) surface: High-resolution imaging of adsorbed sulfate
    Wan, LJ
    Hara, M
    Inukai, J
    Itaya, K
    JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (33): : 6978 - 6983
  • [5] SI(111)-5X1-AU RECONSTRUCTION AS STUDIED BY SCANNING TUNNELING MICROSCOPY
    BASKI, AA
    NOGAMI, J
    QUATE, CF
    PHYSICAL REVIEW B, 1990, 41 (14): : 10247 - 10249
  • [6] Atomic structures of TiO2(110) surface between p(1 x 1) and p(1 x 2) studied by scanning tunneling microscopy
    Asari, E
    Souda, R
    APPLIED SURFACE SCIENCE, 2002, 193 (1-4) : 70 - 76
  • [7] GEOMETRY OF METALLOFULLERENES ADSORBED ON THE SI(100)2X1 SURFACE STUDIED BY SCANNING-TUNNELING-MICROSCOPY
    WANG, XD
    HASHIZUME, T
    XUE, Q
    SHINOHARA, H
    SAITO, Y
    NISHINA, Y
    SAKURAI, T
    CHEMICAL PHYSICS LETTERS, 1993, 216 (3-6) : 409 - 412
  • [8] B-induced reconstruction on Si(100)-(2x1) surface studied with scanning tunneling microscopy
    Hu, YF
    Yang, JS
    Cai, Q
    MATERIALS CHARACTERIZATION, 2002, 48 (2-3) : 183 - 188
  • [9] AN IN-SITU SCANNING-TUNNELING-MICROSCOPY STUDY OF ELECTROCHEMICALLY INDUCED HEX -][-(1X1) TRANSITIONS ON AU(100) ELECTRODES
    MAGNUSSEN, OM
    HOTLOS, J
    BEHM, RJ
    BATINA, N
    KOLB, DM
    SURFACE SCIENCE, 1993, 296 (03) : 310 - 332
  • [10] Atomic hydrogen interaction with the Si(100)4x3-In surface studied by scanning tunneling microscopy
    Ryu, JT
    Kubo, O
    Tani, H
    Katayama, M
    Saranin, AA
    Zotov, AV
    Oura, K
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1998, 37 (6B): : 3774 - 3777
12345