Synthesis and characterization of a new hybrid-metallic complex containing mixed-valence CuI/CuII units generated by hydrothermal redox reaction

被引：6

作者：

Zhao, QH ^{[1
]}

Wang, XF

Liu, YQ

Fang, RB

机构：

[1] Yunnan Univ, Dept Chem, Kunming 650091, Peoples R China

[2] Yunnan Univ, Sch Pharm, Kunming 650091, Peoples R China

[3] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China

来源：

CHEMISTRY LETTERS | 2004年 / 33卷 / 02期

关键词：

D O I：

10.1246/cl.2004.138

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new hybrid-metallic complex containing mixed-valence Cu-I/Cu-II units, [Cu-4(ophen)(4)(Mo2O7)] (Hophen = 2-hydroxy-1,10-phenanthroline), was hydrothermally synthesized and crystallographically characterized.

引用

页码：138 / 139

页数：2

共 23 条

[21] A new coordination mode for tris(2-carboxyethyl)phosphine:: Synthesis, crystal structure and characterization of the mixed-valence Co(III)/Co(II)/Co(III) complex [Co{P(CH2CH2COO)2-(CH2CH2COOH)}2]2[Co(H2O)4][Na2(H2O)4]Cl2 • 6H2O
Knight, D. Andrew
Deschamps, Jeffrey R.
Butcher, Ray J.
Simmers, Christa
Chang, Eddie L.
POLYHEDRON, 2008, 27 (06) : 1795 - 1801
[22] HYDROTHERMAL SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF V(III)-CONTAINING PHASES OF THE VANADIUM ORGANODIPHOSPHONATE SYSTEM - CRYSTAL-STRUCTURES OF THE V(III) SPECIES (H3O)[V-3(O3PCH2CH2PO3)(HO3PCH2CH2PO3H)(3)] AND OF THE MIXED-VALENCE V(III)/V(IV) MATERIAL (H3O)(2)[(VO)V-2(OH)(2)(O3PCH2CH2PO3)(2)]CENTER-DOT-H2O
SOGHOMONIAN, V
HAUSHALTER, RC
ZUBIETA, J
CHEMISTRY OF MATERIALS, 1995, 7 (09) : 1648 - 1654
[23] HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF HEXAVANADIUM POLYOXO ALKOXIDE ANION CLUSTERS - CRYSTAL-STRUCTURES OF THE VANADIUM(IV) SPECIES BA[V6O7(OH)3((OCH2)3CCH3)3].3H2O AND NA2[V6O7((OCH2)3CCH2CH3)4], OF THE MIXED-VALENCE COMPLEX (ME3NH)[VIV5VVO7(OH)3((OCH2)3CCH3)3], AND OF THE FLUORO DERIVATIVE NA[V6O6F(OH)3((OCH2)3CCH3)3].3H2O
KHAN, MI
CHEN, Q
HOPE, H
PARKIN, S
OCONNOR, CJ
ZUBIETA, J
INORGANIC CHEMISTRY, 1993, 32 (13) : 2929 - 2937

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