Three-State Near-Infrared Electrochromism at the Molecular Scale

被引：86

作者：

Cui, Bin-Bin ^{[1
]}

Zhong, Yu-Wu ^{[1
]}

Yao, Jiannian ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Photochem, Beijing 100190, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 12期

基金：

中国国家自然科学基金;

关键词：

ELECTRON-TRANSFER; ELECTROPOLYMERIZED FILMS; VOLATILE MEMORY; MONOLAYERS; COMPLEXES; SURFACES; PLATFORM; DEVICES; LOGIC; ASSEMBLIES;

D O I：

10.1021/jacs.5b00586

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembled monolayer films of a cyclometalated ruthenium complex with a redox-active amine substituent and three carboxylic acid groups have been prepared on ITO electrode surfaces. The obtained thin films show three-state electrochromic switching with low electrochemical potential inputs and high near-infrared absorbance outputs. Thanks to the long retention time of each oxidation states, these films have been used to demonstrate surface-confined flip-flop memory functions with high ON/OFF ratios at the molecular scale.

引用

页码：4058 / 4061

页数：4

共 50 条

[41] NEAR-INFRARED
不详
CHEMTECH, 1992, 22 (09) : 515 - 515
[42] Microwave to Near-infrared Conversion with a Millimeter-scale Wireless Laser for Activating Molecular Transducers
Romano, Anthony
Ho, John S.
2016 38TH ANNUAL INTERNATIONAL CONFERENCE OF THE IEEE ENGINEERING IN MEDICINE AND BIOLOGY SOCIETY (EMBC), 2016, : 352 - 354
[43] Transmissive to black electrochromic aramids with high near-infrared and multicolor electrochromism based on electroactive tetraphenylbenzidine units
Yen, Hung-Ju
Lin, Kun-Ying
Liou, Guey-Sheng
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (17) : 6230 - 6237
[44] Near-infrared detector arrays current state of the art
Hodapp, KW
OPTICAL AND IR TELESCOPE INSTRUMENTATION AND DETECTORS, PTS 1 AND 2, 2000, 4008 : 1228 - 1239
[45] BRAIN OXYGENATION STATE AS MONITORED BY NEAR-INFRARED SPECTROSCOPY
HAZEKI, O
TAMURA, M
YAMAZAKI, I
JAPANESE JOURNAL OF PHARMACOLOGY, 1985, 39 : P358 - P358
[46] Plasmon-induced near-infrared electrochromism based on transparent conducting nanoparticles: Approximate performance limits
Li, S. -Y.
Niklasson, G. A.
Granqvist, C. G.
APPLIED PHYSICS LETTERS, 2012, 101 (07)
[47] SEARCH FOR NEAR-INFRARED EMISSION OF INTERSTELLAR MOLECULAR HYDROGEN
GULL, TR
HARWIT, MO
ASTROPHYSICAL JOURNAL, 1971, 168 (01): : 15 - +
[48] Precision Molecular Engineering of Compact Near-Infrared Fluorophores
Huang, Rongrong
Qiao, Qinglong
Seah, Deborah
Shen, Tianruo
Wu, Xia
de Moliner, Fabio
Wang, Chao
Ding, Nannan
Chi, Weijie
Sun, Huaming
Vendrell, Marc
Xu, Zhaochao
Fang, Yu
Liu, Xiaogang
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2025, 147 (06) : 5258 - 5268
[49] Fluorescence molecular tomography in the second near-infrared window
Wang, Kan
Wang, Qun
Luo, Qingming
Yang, Xiaoquan
OPTICS EXPRESS, 2015, 23 (10): : 12669 - 12679
[50] Near-infrared fluorescence: application to in vivo molecular imaging
Hilderbrand, Scott A.
Weissleder, Ralph
CURRENT OPINION IN CHEMICAL BIOLOGY, 2010, 14 (01) : 71 - 79

← 1 2 3 4 5 →