Synthesis of Conjugated Donor-Acceptor Antiaromatic Porphyrins and Their Application to Perovskite Solar Cells

被引：9
|
作者：
Zheng, Xue-Lin [1 ,2 ]
Lin, Hao-Sheng [3 ,4 ]
Zhang, Bo-Wen [4 ]
Maruyama, Shigeo [4 ]
Matsuo, Yutaka [1 ,2 ,3 ,4 ]
机构：
[1] Univ Sci & Technol China, Sch Chem & Mat Sci, Dept Chem, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
[3] Nagoya Univ, Grad Sch Engn, Dept Chem Syst Engn, Nagoya, Aichi 4648603, Japan
[4] Univ Tokyo, Grad Sch Engn, Dept Mech Engn, Tokyo 1138656, Japan
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 87卷 / 09期
基金：
日本科学技术振兴机构; 日本学术振兴会;
关键词：
SMALL-MOLECULE; FULLERENE; EFFICIENT; RING;
D O I：
10.1021/acs.joc.1c01947
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A conjugated donor-acceptor antiaromatic porphyrin, composed of an antiaromatic thieno-fused porphyrin structure and a diketopyrrolopyrrole mioety, was synthesized and applied in a perovskite solar cell for the first time. Enhanced light absorption in the device by the antiaromatic porphyrin resulted in a significantly increased power conversion efficiency of 19.3%.
引用
收藏
页码：5457 / 5463
页数：7
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