TRANSFER HYDROGENATIONS OF NITROBENZENE USING GLYCEROL AS SOLVENT AND HYDROGEN DONOR

被引：27
|
作者：
Tavor, Dorith [1 ]
Gefen, Ido [1 ]
Dlugy, Christina [1 ]
Wolfson, Adi [1 ]
机构：
[1] Sami Shamoon Coll Engn, Dept Chem Engn, Green Proc Ctr, IL-84100 Beer Sheva, Israel
来源：
SYNTHETIC COMMUNICATIONS | 2011年 / 41卷 / 22期
关键词：
Aniline; catalysis; glycerol; green solvent; transfer hydrogenation; CATALYTIC TRANSFER HYDROGENATION; CHEMOSELECTIVE TRANSFER HYDROGENATION; AROMATIC NITRO-COMPOUNDS; REDUCTION; OXIDATION;
D O I：
10.1080/00397911.2010.518276
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Aniline has been successfully produced by catalytic transfer hydrogenation of nitrobenzene in glycerol, which was employed as both a green solvent and a hydrogen donor. As a solvent, glycerol also facilitated easy separation of the product and recycling of the catalyst.
引用
收藏
页码：3409 / 3416
页数：8
相关论文
共 50 条
  • [41] Castor oil hydrogenation by a catalytic hydrogen transfer system using limonene as hydrogen donor
    Martinelli, M. (marciam@iq.ufrgs.br), 1600, American Oil Chemists' Society (82):
  • [42] Castor oil hydrogenation by a catalytic hydrogen transfer system using limonene as hydrogen donor
    Martinelli, M
    Schneider, RDD
    Baldissarelli, VZ
    von Holleben, ML
    Caramao, EB
    JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2005, 82 (04) : 279 - 283
  • [43] Palladium/Carbon Catalyzed Hydrogen Transfer Reactions using Magnesium/Water as Hydrogen Donor
    Omari Muhammad
    Sachin U. Sonavane
    Yoel Sasson
    Mandan Chidambaram
    Catalysis Letters, 2008, 125 : 46 - 51
  • [44] PALLADIUM-CATALYZED AND SONICALLY ACCELERATED HYDROGENATIONS OF OLEFINS USING FORMIC-ACID AS A HYDROGEN TRANSFER AGENT
    BOUDJOUK, P
    HAN, BH
    JOURNAL OF CATALYSIS, 1983, 79 (02) : 489 - 492
  • [45] Nitrobenzene as hydrogen acceptor in Pd/C-catalyzed hydrogen transfer reaction
    Tanaka, T
    Kawabata, H
    Hayashi, M
    TETRAHEDRON LETTERS, 2005, 46 (30) : 4989 - 4991
  • [46] Synthesis of p-aminophenol by transfer hydrogenation of nitrobenzene using formic acid as hydrogen source
    Wang, Yufei
    Jia, Yu
    Zhang, Yisheng
    Xue, Wei
    Li, Fang
    Wang, Yanji
    Huagong Jinzhan/Chemical Industry and Engineering Progress, 2024, 43 (08): : 4421 - 4431
  • [47] Regulation of the Properties of Hydrogen Dissociation and Transfer in the Presence of S Atoms for Efficient Hydrogenations
    Liu, Xiaoyan
    Zhang, Mingyuan
    Liu, Xin
    Liu, Jiali
    Dai, Huicong
    Luo, Wenhao
    Liu, Jian
    Gao, Rui
    Yang, Qihua
    ACS CATALYSIS, 2024, 14 (21): : 16214 - 16223
  • [48] Mechanistic Aspects of Using Formate as a Hydrogen Donor in Aqueous Transfer Hydrogenation
    Pavlova, Anna
    Rosler, Ernst
    Meijer, Evert Jan
    ACS CATALYSIS, 2016, 6 (08): : 5350 - 5358
  • [49] Purification of Red Palm Biodiesel by Using K2CO3 Based Deep Eutectic Solvent (DES) with Glycerol as Hydrogen Bond Donor (HBD)
    Manurung, Renita
    Arief, Aulia
    Hutauruk, Gilang Ramadhan
    HUMAN-DEDICATED SUSTAINABLE PRODUCT AND PROCESS DESIGN: MATERIALS, RESOURCES, AND ENERGY, 2018, 1977
  • [50] ABSORPTION SPECTRA OF NITROBENZENE DERIVATIVES .2. EFFECT OF SOLVENT ON INTRAMOLECULAR CHARGE TRANSFER SPECTRA OF NITROBENZENE DERIVATIVES
    SEMBA, K
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1961, 34 (05) : 722 - 728
12345