Synthesis and properties of quick-drying UV-curable hyperbranched waterborne polyurethane coating

被引:30
|
作者
Boton, Lilian [1 ]
Puguan, John Marc [1 ]
Latif, Muhammad [1 ]
Kim, Hern [1 ]
机构
[1] Myongji Univ, Smart Living Innovat Technol Ctr, Dept Energy Sci & Technol, Yongin 17058, Gyeonggi Do, South Korea
基金
新加坡国家研究基金会;
关键词
UV-curing; Waterborne hyperbranched PU; Irgacure; 184; Trimethylol propane; ACRYLATE; PHOTOPOLYMERIZATION; DISPERSIONS;
D O I
10.1016/j.porgcoat.2018.09.017
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Ultraviolet light (UV)-curable hyperbranched waterborne polyurethane (UVHWPU) resins were synthesized using polypropylene glycol (PPG)-1000, dimethylol propionic acid (DMPA), trimethylol propane (TMP), isophorone diisocyanate (IPDI) as core moiety, and 2-hydroxyethyl methacrylate (HEMA) as capping agent. The preparation methods of the UVHWPU resins were studied and an optimum recipe was given by selecting the proper dosage of DMPA, PPG-1000 and TMP. The structure of hyperbranched resins was characterized by C-13-NMR spectra and Fourier transform infrared (FTIR) spectroscopy. The type and dosage of photoinitiator were determined, and the properties of UVHWPU coating with excellent performance were examined.
引用
收藏
页码:201 / 206
页数:6
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