Hydrogen-bonded assemblies of trinuclear metal string complexes

被引：5
|
作者：
Li, Hui [1 ]
Yan, Jun
Xu, Ying Ying
Gao, Wen Gui
Lee, Gene-Hsiang
Peng, Shie-Ming
机构：
[1] Beijing Inst Technol, Dept Chem, Beijing 100081, Peoples R China
[2] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan
[3] Acad Sinica, Inst Chem, Taipei 115, Taiwan
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 60卷 / 22-24期
关键词：
metal string complexes; bis(2-pyridyl)amido; polynuclear nickel complexes; hydrogen-bonded network; acrylic acid;
D O I：
10.1080/00958970701308682
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three kinds of trinuclear metal string complexes, [Ni-3(dpa)(4)(L-1)(2)]center dot H2O center dot C2H5OH (L-1 = (E)-3-(2-hydroxyl-phenyl)- acrylic acid) (1), [Ni-3(dpa)(4)(L-2)(2)]center dot 2C(2)H(5)OC(2)H(5) (L-2 =(E)-3-(3-hydroxyl-phenyl)- acrylic acid) (2) mid [Ni-3(dpa)(4)(L-2)(2)]center dot 3CH(2)Cl(2)center dot 1.5CH(3)OH (L-3 =(E)-3-(4-hydroxyl-phenyl)-acrylic acid) (3). (dpa(-) = bis(2-pyridyl)amido), have been synthesized. The structures of 1 and 2 have been analyzed by the X-ray single-crystal diffraction showing hydrogen-bonded networks.
引用
收藏
页码：2731 / 2738
页数：8
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